{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T13:01:25Z","timestamp":1778072485744,"version":"3.51.4"},"reference-count":51,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2025,7,14]],"date-time":"2025-07-14T00:00:00Z","timestamp":1752451200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278337"],"award-info":[{"award-number":["22278337"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Directly converting methane into high\u2010value\u2010added chemicals presents a significant challenge in catalysis. Nonthermal plasma (NTP) offers an efficient approach for direct methanol synthesis through methane activation. However, theoretical frameworks for designing catalysts under NTP conditions remain underdeveloped. It is quite difficult to control the assembly process of radical species on catalyst surfaces. A boron nitride (BN)\u2010confined Fe single\u2010atom catalysts (Fe\u2010SACs) is synthesized by in situ anchoring in defect sites induced by mechanical ball milling. This catalyst is utilized for NTP\u2010catalyzed direct methane\u2010to\u2010methanol conversion. The results demonstrate that the CH\n                    <jats:sub>3<\/jats:sub>\n                    OH yield increases by \u22482.5 times compared to conditions with NTP alone, while selectivity doubles. The experimental results and theoretical calculations indicate that \u00b7OH radicals generated by the dissociation of H\n                    <jats:sub>2<\/jats:sub>\n                    O are rapidly adsorbed by Fe\u2010SACs before annihilation. This process facilitates the stabilization of \u00b7CH\n                    <jats:sub>3<\/jats:sub>\n                    species and enhances the kinetics of CH\n                    <jats:sub>3<\/jats:sub>\n                    OH assembly along the E\u2010R reaction pathway. A design criterion is proposed for plasma\u2010catalyzed radical adsorption intensification\u2010directed assembly catalysts, offering a novel approach for the directional catalytic conversion of reactants through radical pathways.\n                  <\/jats:p>","DOI":"10.1002\/smll.202504512","type":"journal-article","created":{"date-parts":[[2025,7,14]],"date-time":"2025-07-14T18:50:47Z","timestamp":1752519047000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Directional Assembly of Radicals to Methanol in CH\n                    <sub>4<\/sub>\n                    \/H\n                    <sub>2<\/sub>\n                    O Plasma Mediated by BN\u2010Confined Single Iron Atoms"],"prefix":"10.1002","volume":"21","author":[{"given":"Xiang","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Northwest University  Xi'an 710069 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