{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T16:42:40Z","timestamp":1790181760177,"version":"4.1.0"},"reference-count":86,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T00:00:00Z","timestamp":1749686400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFA1500401"],"award-info":[{"award-number":["2021YFA1500401"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92461302"],"award-info":[{"award-number":["92461302"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101305"],"award-info":[{"award-number":["22101305"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21771197"],"award-info":[{"award-number":["21771197"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22003079"],"award-info":[{"award-number":["22003079"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301316"],"award-info":[{"award-number":["22301316"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010002","name":"Ministry of Education","doi-asserted-by":"publisher","award":["22qntd2303"],"award-info":[{"award-number":["22qntd2303"]}],"id":[{"id":"10.13039\/100010002","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2022M713565"],"award-info":[{"award-number":["2022M713565"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Visible light\u2010driven photocatalytic reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to value\u2010added fuels and chemicals has attracted extensive interest for decades. However, the emerging photocatalysis paradigm through an interband transition in non\u2010plasmonic metals remains challenging. Herein, a new strategy, namely hot carrier exploitation is demonstrated, for highly efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction through the interband transition in non\u2010plasmonic Ru nanoparticles (NPs). The Ru NPs are integrated with a metal\u2013organic framework (MOF) to construct a Schottky junction of Ru@MOF\u2010808, which features a directed injection of hot interband electrons from Ru NPs to adsorbed substrates, and localized enrichment and activation of substrates around Ru catalytic centers, due to its high Schottky barrier, superior gas adsorption capacity, and excellent hydrogen spillover capability. Hot interband holes in Ru NPs can also be promptly quenched by enriched active H species, ensuring sustainable hot electron generation and producing abundant protons for CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation. Such catalyst design enables highly efficient utilization of hot interband carriers, and in turn, substantially accelerates the kinetically challenging CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation involving 8 electrons and 8 protons. Consequently, Ru@MOF\u2010808 delivers a record\u2010high apparent quantum yield of 17.16% under visible light and ambient conditions. The finding provides new insights into heterogeneous photocatalysis, and opens up a new avenue to efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization.\n                  <\/jats:p>","DOI":"10.1002\/smll.202504721","type":"journal-article","created":{"date-parts":[[2025,6,13]],"date-time":"2025-06-13T01:35:52Z","timestamp":1749778552000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Hot Interband Carrier Exploitation in a Ru\/MOF Schottky Junction for Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"21","author":[{"given":"Shunlian","family":"Ning","sequence":"first","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuodi","family":"Chen","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huanfeng","family":"Huang","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihui","family":"Liu","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yushuo","family":"He","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3471-5744","authenticated-orcid":false,"given":"Dawei","family":"Wang","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanan","family":"Fan","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng\u2010Xia","family":"Chen","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0042-9483","authenticated-orcid":false,"given":"Mihail","family":"Barboiu","sequence":"additional","affiliation":[{"name":"Institut Europeen des Membranes Adaptive Supramolecular Nanosystems Group University of Montpellier  ENSCM\u2010CNRS, UMR5635, Place E. Bataillon CC047 Montpellier 34095 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3604-7858","authenticated-orcid":false,"given":"Cheng\u2010Yong","family":"Su","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering Lehn Institute of Functional Materials IGCME School of Chemistry Sun Yat\u2010Sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31474-2"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01712"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00490-z"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egyr.2022.10.127"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cherd.2023.11.060"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53336-9"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.2c00655"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02585"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.11.009"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0016-y"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c00810"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313209"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202200057"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c05984"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-00858-4"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c08561"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnanoscienceau.4c00035"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00165"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2022.103737"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c04431"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11443"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.136482"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2025.110672"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8044"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.7b00122"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c02325"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.138392"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-21925-7"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011805"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312616"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.11.098"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122231"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202100487"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA13275A"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja500330a"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116396"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.55.4783"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1380\/ejssnt.2020.133"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206108"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201711725"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304652"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04062"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40117-z"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301925"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201700194"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.3c04436"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00060"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202213124"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202400769"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10278D"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.03.034"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11355-x"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601657"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.01.007"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03283"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE03643A"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b15992"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/lno.10366"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2023.119166"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05542-5"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0054-3"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp074549x"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c01296"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2023.12.178"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.2174\/1874478810801010052"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA01600E"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00058"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY02462B"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b04469"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124549"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803514"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY01656A"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemphys.2022.111546"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp075787v"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2004.03.007"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp055908w"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2071384"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c07825"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(98)00504-5"},{"key":"e_1_2_8_80_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27910-4"},{"key":"e_1_2_8_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp108106t"},{"key":"e_1_2_8_82_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9517(92)90079-W"},{"key":"e_1_2_8_83_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.02.017"},{"key":"e_1_2_8_84_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CY00478D"},{"key":"e_1_2_8_85_1","doi-asserted-by":"publisher","DOI":"10.1039\/f19888400511"},{"key":"e_1_2_8_86_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00584"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202504721","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,21]],"date-time":"2025-11-21T14:52:41Z","timestamp":1763736761000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202504721"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,12]]},"references-count":86,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2025,8]]}},"alternative-id":["10.1002\/smll.202504721"],"URL":"https:\/\/doi.org\/10.1002\/smll.202504721","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,12]]},"assertion":[{"value":"2025-04-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-12","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2504721"}}