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These heterostructures are incorporated into a 3D network of nitrogen\u2010doped carbon\u2010nanotubes (NCNTs) supported by carbon\u2010cloth, resulting in the p\u2010Mn\u2010NiCo\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    @Co\n                    <jats:sub>2<\/jats:sub>\n                    N\/NCNTs. It demonstrates excellent bifunctional catalytic activity, with a potential difference (\u0394E = E\n                    <jats:sub>OER,50<\/jats:sub>\n                    \u2010E\n                    <jats:sub>ORR,1\/2<\/jats:sub>\n                    ) as low as 0.695 V. The half\u2010wave potential of oxygen\u2010reduction reaction (ORR) is 0.828 V, and the overpotential for oxygen\u2010evolution reaction (OER) to achieve 50 mA cm\u207b\n                    <jats:sup>2<\/jats:sup>\n                    is only 293 mV. Density\u2010Functional\u2010Theory (DFT) calculations confirm that the exceptional catalytic activity originates from the V\n                    <jats:sub>S<\/jats:sub>\n                    and Mn\u2010doping structure. The assembled liquid zinc\u2010air battery (ZAB) has an open\u2010circuit voltage (OCV) of 1.54 V, a peak power\u2010density of 139.9 mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and can undergo stable charge\/discharge cycles for 1500 cycles at 10 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The assembled flexible all\u2010solid\u2010state ZAB also features a stable OCV of 1.486 V and exhibits a peak power\u2010density superior to that of commercial 20 wt.% Pt\/C+RuO\n                    <jats:sub>2<\/jats:sub>\n                    , accompanied by stable charging\/discharging cycles of up to 700 cycles. The performance remains stable across various bending angles, demonstrating good flexibility and durability. The maximum power\u2010density exhibited by alkaline direct methanol fuel\u2010cells (ADMFCs) assembled with p\u2010Mn\u2010NiCo\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    @Co\n                    <jats:sub>2<\/jats:sub>\n                    N\/NCNTs is 75.6 mW cm\u207b\n                    <jats:sup>2<\/jats:sup>\n                    , exceeding that of the commercial Pt\/C catalyst.\n                  <\/jats:p>","DOI":"10.1002\/smll.202504987","type":"journal-article","created":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T10:01:48Z","timestamp":1750068108000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Plasma\u2010Induced S\u2010Vacancy and Mn\u2010Doping Synergistically Boost the Catalytic Activity of NiCo\n                    <sub>2<\/sub>\n                    S\n                    <sub>4<\/sub>\n                    @Co\n                    <sub>2<\/sub>\n                    N Heterostructure for Rechargeable Zinc\u2010Air Batteries and Alkaline Methanol Fuel Cells"],"prefix":"10.1002","volume":"21","author":[{"given":"Hao","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Physics Zhejiang Key Laboratory of Quantum State Control and Optical Field Manipulation Zhejiang Sci\u2010Tech University  Hangzhou 310018 P. R. China"},{"name":"Department of Materials and Chemical Engineering Ningbo University of Technology  Ningbo 315211 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shenchen","family":"Jiang","sequence":"additional","affiliation":[{"name":"Department of Physics Zhejiang Key Laboratory of Quantum State Control and Optical Field Manipulation Zhejiang Sci\u2010Tech University  Hangzhou 310018 P. R. China"},{"name":"Department of Materials and Chemical Engineering Ningbo University of Technology  Ningbo 315211 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Physics Zhejiang Key Laboratory of Quantum State Control and Optical Field Manipulation Zhejiang Sci\u2010Tech University  Hangzhou 310018 P. R. China"},{"name":"Department of Materials and Chemical Engineering Ningbo University of Technology  Ningbo 315211 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiheng","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Ningbo University of Technology  Ningbo 315336 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong\u2010Jie","family":"Jiang","sequence":"additional","affiliation":[{"name":"Guangzhou Key Laboratory for Surface Chemistry of Energy Materials Guangdong Engineering and Technology Research Center for Surface Chemistry of Energy Materials College of Environment and Energy South China University of Technology  Guangzhou 510006 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoning","family":"Tian","sequence":"additional","affiliation":[{"name":"Department of Materials and Chemical Engineering Ningbo University of Technology  Ningbo 315211 P. R. 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