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Herein, by synergistically exploiting the energetic hot carriers and photogenerated electron\u2010hole pairs generated by plasmonic Au\/Ru assembled on wide bandgap TiO\n                    <jats:sub>2<\/jats:sub>\n                    nanowire array (TiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010NWs), an ultra\u2010low charge overpotential and high energy efficiency solid\u2010state Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    battery via plasmon\u2010enhanced Au\/Ru\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010NWs cathode, where solar energy can be efficiently harvested (over 96% absorptivity from 200 to 1500\u00a0nm), concentrated, and converted on the cathode is reported. The dual\u2010active\u2010site design of the Au\/Ru catalysts not only enhances the localized surface plasmon resonance, but also facilitates CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction and evolution reaction kinetics by reducing the reaction kinetic barriers. As a result, the solid\u2010state Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    battery based on Au\/Ru\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    cathode achieves a record ultra\u2010low charging potential (\u22482.57\u00a0V) and high energy efficiency (\u224896.1%), far exceeding that of reported Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries. Notably, the battery remains \u22482.64\u00a0V charge potential and \u224895.3% energy efficiency after 150\u00a0h. This work paves a way for developing high\u2010energy\u2010efficiency solid\u2010state battery with a carbon neutral effect.\n                  <\/jats:p>","DOI":"10.1002\/smll.202505366","type":"journal-article","created":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T11:56:23Z","timestamp":1753876583000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["An Ultra\u2010Low Discharge and High Energy Efficiency Li\u2010CO\n                    <sub>2<\/sub>\n                    Battery Enabled by Plasmon\u2010Enhanced AuRu\u2010TiO\n                    <sub>2<\/sub>\n                    Bifunctional Cathode"],"prefix":"10.1002","volume":"21","author":[{"given":"Xiaoying","family":"Song","sequence":"first","affiliation":[{"name":"School of Optoelectronic Engineering Chongqing University of Posts and Telecommunications  Chongqing 400065 P. R. 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