{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T03:47:02Z","timestamp":1783741622245,"version":"3.55.0"},"reference-count":58,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2025,7,10]],"date-time":"2025-07-10T00:00:00Z","timestamp":1752105600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22178119"],"award-info":[{"award-number":["22178119"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378137"],"award-info":[{"award-number":["22378137"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378137"],"award-info":[{"award-number":["22378137"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2024A1515010948"],"award-info":[{"award-number":["2024A1515010948"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2023A1515030274"],"award-info":[{"award-number":["2023A1515030274"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The rapid removal of trace formaldehyde and particulate matter (PM) from indoor environments via adsorption and filtration remains a significant challenge. Herein, a series of MOFs@PAN composite membranes with dense adsorption sites and enhanced electrostatic interactions are engineered for efficient formaldehyde capture and PM filtration. The 72%\u2010Mg\u2010MOF\u201074@PAN membrane demonstrated a remarkable HCHO adsorption capacity of 36.39\u00a0mg\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (1\u00a0ppm, 303 K) and a breakthrough adsorption capacity of 106.11\u00a0mg\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (10\u00a0ppm, 298 K), surpassing that of commercial activated carbon (1.23\u00a0mg\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and ZIF\u201067@ANF (MOFs, 5.31\u00a0mg\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). The superior trace HCHO adsorption originates from strong electrostatic interactions between unsaturated Mg clusters and HCHO, coupled with densely distributed adsorption sites within the framework. Furthermore, the 72%\u2010Mg\u2010MOF\u201074@PAN membrane exhibited a particle filtration efficiency of over 99.5% for PM\n                    <jats:sub>0.3<\/jats:sub>\n                    . The PM\n                    <jats:sub>0.3<\/jats:sub>\n                    capture mechanism synergistically integrated passive structural diffusional deposition mediated by the ultrafine PAN fibers (0.25\u00a0\u00b5m) and proactive electrostatic entrapment driven by surface hydroxyl groups and unsaturated metal sites. This research underscores the exceptional performance of Mg\u2010MOF\u201074@PAN membranes in improving indoor air quality, efficiently eliminating formaldehyde and proficiently filtering PM\n                    <jats:sub>0.3<\/jats:sub>\n                    particles.\n                  <\/jats:p>","DOI":"10.1002\/smll.202506011","type":"journal-article","created":{"date-parts":[[2025,7,11]],"date-time":"2025-07-11T06:44:56Z","timestamp":1752216296000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Mg\u2010MOF\u201074@PAN Nanofibrous Membranes: Synergistic Purification of Trace Formaldehyde and Particulate Matter"],"prefix":"10.1002","volume":"21","author":[{"given":"Xingbei","family":"Wu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shi","family":"Tu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofei","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajin","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinze","family":"Yao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 P. R. China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang 515200 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Mu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"},{"name":"School for Engineering of Matter Transport, and Energy Arizona State University  Tempe Arizona 85287 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8563-6715","authenticated-orcid":false,"given":"Qibin","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510641 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.3389\/fpubh.2020.00014"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-024-00427-3"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.buildenv.2017.03.004"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2020.110065"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2018.12.011"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00408"},{"key":"e_1_2_7_7_1","unstructured":"WHO\u2010ROE R. O. o. E. World Health Organization Bonn Germany2006."},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envint.2009.06.002"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1111\/ina.13141"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c06520"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2022.120728"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-023-00309-0"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c06565"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10311-020-01168-6"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2010.10.008"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12273-016-0281-8"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2005.10.044"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2022.115269"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2024.142550"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.123634"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2020.11.023"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215119"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-019-04142-y"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano9030338"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.03.098"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c01630"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.123887"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2019.121161"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2022.112136"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2024.119769"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2017.05.013"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2020.103986"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.127459"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.2c01721"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.130345"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2TA00028H"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.127347"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.07.186"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b17479"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9QI01564G"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201901100"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b06713"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.122074"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC03132G"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139669"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02553"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201902590"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.3c05053"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2019.03.075"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15193965"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.4c06225"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201909554"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2022.03.012"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2024.134781"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202312022"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12221-024-00831-x"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08752"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7205"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202506011","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T22:29:15Z","timestamp":1764109755000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202506011"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,10]]},"references-count":58,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2025,9]]}},"alternative-id":["10.1002\/smll.202506011"],"URL":"https:\/\/doi.org\/10.1002\/smll.202506011","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,10]]},"assertion":[{"value":"2025-05-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2506011"}}