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Herein, the core\u2013shell structure of polyoxovanadates {Mn\n                    <jats:sub>3<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>12<\/jats:sub>\n                    V\n                    <jats:sub>18<\/jats:sub>\n                    O\n                    <jats:sub>42<\/jats:sub>\n                    (SO\n                    <jats:sub>4<\/jats:sub>\n                    )} (MnVO) coated with polyaniline (PANI) is developed as the cathode material for AZIBs. The tri\u2010dimensional robust MnVO offers abundant active sites and high porosity, and the highly conductive PANI significantly accelerates the electron\/ion transfer transport and prevents the dissolution of polyoxovanadates, which effectively enhance reaction kinetics and provide sufficient space for improving Zn\n                    <jats:sup>2+<\/jats:sup>\n                    storage performance. Consequently, the optimized MnVO@PANI cathode exhibited a high reversible capacity of 413.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and excellent cyclic stability with 85.4% capacity retention at 10 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 1500 cycles.\n                  <\/jats:p>","DOI":"10.1002\/smll.202506528","type":"journal-article","created":{"date-parts":[[2025,8,6]],"date-time":"2025-08-06T09:51:23Z","timestamp":1754473883000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Core\u2013Shell Structure of Polyoxovanadate Coated with Polyaniline for High\u2010Performance Aqueous Zinc\u2010Ion Battery Cathode Materials"],"prefix":"10.1002","volume":"21","author":[{"given":"Wen\u2010Fei","family":"Di","sequence":"first","affiliation":[{"name":"College of Chemistry and Materials Science Sichuan Normal University  Chengdu 610066 P. 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