{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T23:42:12Z","timestamp":1791330132347,"version":"4.3.1"},"reference-count":55,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB4400100"],"award-info":[{"award-number":["2022YFB4400100"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB4400101"],"award-info":[{"award-number":["2022YFB4400101"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22375040"],"award-info":[{"award-number":["22375040"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2321002"],"award-info":[{"award-number":["T2321002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22125501"],"award-info":[{"award-number":["22125501"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20152"],"award-info":[{"award-number":["U22A20152"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["2024ZDSYS02"],"award-info":[{"award-number":["2024ZDSYS02"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["RF1028623031"],"award-info":[{"award-number":["RF1028623031"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2242025F10007"],"award-info":[{"award-number":["2242025F10007"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Transition metal dichalcogenides (TMDs) have attracted significant attention in electronic devices, energy storage, and catalysis owing to their distinctive electronic properties and abundant active sites. Introducing mesoporosity into TMDs is extremely favorable to enhance the host\u2010guest interactions and improve their performance, but very challenging. Herein, we report a universal electrostatic assembly strategy for the synthesis of mesoporous carbon\/heteroatom\u2010doped TMDs microspheres with radially oriented pores, using polydopamine (PDA) and polyoxometalates (POMs) clusters as interactive precursors. By employing POMs (e.g., H\n                    <jats:sub>3<\/jats:sub>\n                    PW\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>40<\/jats:sub>\n                    ) as metal sources and mesoporous PDA microspheres as templates, we successfully synthesized a series of mesoporous C\/heteroatom\u2010doped TMDs microspheres (TMDs\u00a0=\u00a0P\u2010WS\n                    <jats:sub>2<\/jats:sub>\n                    , Si\u2010WS\n                    <jats:sub>2<\/jats:sub>\n                    , P\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    , Si\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    ). The resulting hybrid microspheres feature an open porous architecture, high charge\u2010carrier mobility, and abundant active sites, benefiting from their high crystallinity and in situ heteroatom doping. When employed in chemiresistive gas sensors, these C\/TMDs microspheres demonstrate exceptional room\u2010temperature NO\n                    <jats:sub>2<\/jats:sub>\n                    sensing performance, including high sensitivity, excellent selectivity, and rapid response. Density functional theory (DFT) calculations reveal that heteroatom doping (e.g., P) can enhance the structural stability of adsorbed NO\n                    <jats:sub>2<\/jats:sub>\n                    , strengthen orbital hybridization with TMDs, and facilitate efficient charge transfer, thereby dramatically improving sensing performances.\n                  <\/jats:p>","DOI":"10.1002\/smll.202506929","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T11:05:52Z","timestamp":1767870352000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Heteroatoms\u2010doped Transition Metal Dichalcogenides Confined in Mesoporous Nitrogen\u2010doped Carbon Microspheres With Radial Pores for NO\n                    <sub>2<\/sub>\n                    Sensing"],"prefix":"10.1002","volume":"22","author":[{"given":"Rui","family":"Ma","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenliang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujian","family":"Rao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueqiong","family":"Cui","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tuo","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zejun","family":"Han","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiongfeng","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Electronic Science and Engineering Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0657-9397","authenticated-orcid":false,"given":"Yonghui","family":"Deng","sequence":"additional","affiliation":[{"name":"Department of Chemistry State Key Laboratory of Coatings for Advanced Equipment Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Tao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,8]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00631"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201007438\u20105"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202420060"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201008759\u20109"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-025-02170-5"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055073\u20105"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ado7489"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202503917"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16536"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418757"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.55"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202414800"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005306\u20108"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202203594"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00361"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010019\u20100542\u2010x"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202113348"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42114\u2010024\u201000922\u20106"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.201701167"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010024\u201001799\u20108"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010024\u201001693\u20109"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418344"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk9089"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153703"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010021\u201000951\u20103"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja072910n"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00236"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201501937"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201501814"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42254\u2010024\u201000781\u20106"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408426"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202400376"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202107439"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abq2356"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07938"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00761D"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02091"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202002488"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913492"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/b007111k"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08133"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704779"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002584"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201008492\u20109"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.8b08778"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055534\u2010x"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b05811"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2015.10.077"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1186\/s11671\u2010020\u201003391\u20100"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010024\u201002069\u20107"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202404923"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c11475"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153703"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c03549"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA03660C"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202506929","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202506929","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202506929","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:26:23Z","timestamp":1784305583000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202506929"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,8]]},"references-count":55,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2026,3]]}},"alternative-id":["10.1002\/smll.202506929"],"URL":"https:\/\/doi.org\/10.1002\/smll.202506929","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,8]]},"assertion":[{"value":"2025-06-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e06929"}}