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However, dendritic Li formation poses significant challenges, leading to performance degradation and safety hazards. This study emphasizes the importance of controlling the functional edge structures of benzene\u2010derived molecular electrolyte additives to achieve rapid and long\u2010term LMB performance, thereby proposing benzoate sodium salt (BZ\u2010COO) as a promising candidate. Finally, Li\u2010Li symmetric cells employing BZ\u2500COO exhibit exceptional cycling performance over 1600 cycles even under harsh conditions (5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), outperforming benzene additives with \u2500CH\n                    <jats:sub>3<\/jats:sub>\n                    or \u2500CHO substituents. This study provides a novel perspective on the development of surface flattening electrolyte additives for rapid operation and extended lifespan of LMBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.202507079","type":"journal-article","created":{"date-parts":[[2025,8,11]],"date-time":"2025-08-11T06:22:21Z","timestamp":1754893341000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Tuning Interface Dynamics of Benzene\u2010Based Molecular Dipoles for High Capacity and Long Lifespan in Lithium Metal Batteries"],"prefix":"10.1002","volume":"21","author":[{"given":"Chae Yeong","family":"Son","sequence":"first","affiliation":[{"name":"Department of Chemical and Biological Engineering Sookmyung Women's University  100 Cheongpa\u2010ro 47\u2010gil, Yongsan\u2010gu Seoul 04310 Republic of 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