{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T14:22:13Z","timestamp":1792160533300,"version":"4.4.0"},"reference-count":67,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2025,7,24]],"date-time":"2025-07-24T00:00:00Z","timestamp":1753315200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22372084"],"award-info":[{"award-number":["22372084"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Deblocking the constraints for charge transfer dynamics spanning the spatiotemporal scale from femtosecond to second along with spatial scale from atom to micrometer displays a significant challenge in liberating photocatalysis efficiency. Herein, the challenge is well addressed by\n                    <jats:italic>d\u2010p<\/jats:italic>\n                    spin\u2010orbit coupling from spin\u2010state FeS\n                    <jats:sub>2<\/jats:sub>\n                    to amplify CdS polarization for exceptional H\n                    <jats:sub>2<\/jats:sub>\n                    photocatalytic generation. The spin\u2010polarized states amplified by the upshift energy levels of Fe 3\n                    <jats:italic>d<\/jats:italic>\n                    and Cd 3\n                    <jats:italic>d<\/jats:italic>\n                    vectorially boost charge carrier transfer dynamics at spatial redox active sites with extending nanosecond lifetime up to 2.48 times; remarkably, energy barrier for chemical adsorption and activation of\n                    <jats:sup>*<\/jats:sup>\n                    H and\n                    <jats:sup>*<\/jats:sup>\n                    OH at S 2\n                    <jats:italic>p<\/jats:italic>\n                    from FeS\n                    <jats:sub>2<\/jats:sub>\n                    and Cd 3\n                    <jats:italic>d<\/jats:italic>\n                    of CdS are decreased by their electron transfer into the corresponding unoccupied orbits, respectively, performing Volmer\u2010Heyrovsky and Volmer\u2010Tafel paths for H\n                    <jats:sub>2<\/jats:sub>\n                    generation with activation energy down to 70.77%. As a result, the amplified spin\u2010polarized catalyst presents an exceptional productivity of 3.16% at 25\u00a0\u00b0C or 8.00% at 60\u00a0\u00b0C for solar energy conversion into H\n                    <jats:sub>2<\/jats:sub>\n                    at AM 1.5G, being one of the most efficient H\n                    <jats:sub>2<\/jats:sub>\n                    \u2010evolution catalysts for photocatalytic H\n                    <jats:sub>2<\/jats:sub>\n                    O overall splitting.\n                  <\/jats:p>","DOI":"10.1002\/smll.202507554","type":"journal-article","created":{"date-parts":[[2025,7,25]],"date-time":"2025-07-25T06:40:41Z","timestamp":1753425641000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Spin\u2010Orbit Coupling Amplifying Polarization State for Regulating Bulk Charge Vectorial Transfer Dynamics at Spatiotemporal Scale for Towering H\n                    <sub>2<\/sub>\n                    Generation"],"prefix":"10.1002","volume":"21","author":[{"given":"Yiting","family":"Lin","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Chemical Engineering Ningbo University  Ningbo 315211 P. 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