{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:40:54Z","timestamp":1785890454300,"version":"3.56.0"},"reference-count":27,"publisher":"Wiley","issue":"51","license":[{"start":{"date-parts":[[2025,11,14]],"date-time":"2025-11-14T00:00:00Z","timestamp":1763078400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,11,14]],"date-time":"2025-11-14T00:00:00Z","timestamp":1763078400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The urgent need to combat global warming inspired the introduction of the concept of carbon dioxide direct air capture (CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010DAC), a key strategy for decentralized greenhouse gas removal from air. In this study, a simple approach for CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010DAC is introduced, utilizing ZSM\u20105 and its ion\u2010exchanged analogues to effectively concentrate CO\n                    <jats:sub>2<\/jats:sub>\n                    from humid air (80% RH) at 5\u00a0\u00b0C and enable its recovery at a moderate desorption temperature of 25\u00a0\u00b0C where in both cases, ambient air served as a sustainable CO\n                    <jats:sub>2<\/jats:sub>\n                    source and desorption medium. Repeated adsorption (5\u00a0\u00b0C) and desorption (25\u00a0\u00b0C) cycles confirm the adsorbent stability under realistic conditions. Based on Monte Carlo (MC) and molecular dynamics (MD) simulations, a preferential CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption via electrostatic interactions with minimal competitive adsorption with H\n                    <jats:sub>2<\/jats:sub>\n                    O is observed, explained by the facile diffusion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into the micropores compared to the preferred H\n                    <jats:sub>2<\/jats:sub>\n                    O adsorption on the outer surface of the zeolite. These experimental and theoretical insights pave the way for industrial CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010DAC applications using zeolite\u2010based adsorbents.\n                  <\/jats:p>","DOI":"10.1002\/smll.202508150","type":"journal-article","created":{"date-parts":[[2025,11,14]],"date-time":"2025-11-14T19:17:44Z","timestamp":1763147864000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Direct Air Capture of Carbon Dioxide into MFI Frameworks by Low\u2010Temperature Swing Under Realistic Humidity"],"prefix":"10.1002","volume":"21","author":[{"given":"Sebastian","family":"L\u00f6bner","sequence":"first","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5933-5249","authenticated-orcid":false,"given":"Ashour A.","family":"Ahmed","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2723-1904","authenticated-orcid":false,"given":"Majid Namayandeh","family":"Jorabchi","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Wotzka","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marion","family":"St\u00f6hr","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oliver","family":"Gr\u00f6ger","sequence":"additional","affiliation":[{"name":"Group Innovation\u2010CO2 Economy Volkswagen AG  38436 Wolfsburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christine","family":"Sch\u00fctz","sequence":"additional","affiliation":[{"name":"Group Innovation\u2010CO2 Economy Volkswagen AG  38436 Wolfsburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marc","family":"R\u00fcggeberg","sequence":"additional","affiliation":[{"name":"Group Innovation\u2010CO2 Economy Volkswagen AG  38436 Wolfsburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1407-7263","authenticated-orcid":false,"given":"Sebastian","family":"Wohlrab","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4160-0611","authenticated-orcid":false,"given":"Ali M.","family":"Abdel\u2010Mageed","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institute for Catalysis  Albert\u2010Einstein\u2010Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,14]]},"reference":[{"key":"e_1_2_7_1_1","first-page":"740","volume":"55","author":"Horowitz C. 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