{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,12]],"date-time":"2026-06-12T04:34:52Z","timestamp":1781238892234,"version":"3.54.1"},"reference-count":42,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T00:00:00Z","timestamp":1761350400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100017596","name":"Natural Science Basic Research Program of Shaanxi Province","doi-asserted-by":"publisher","award":["2025JC\u2010YBQN\u2010195"],"award-info":[{"award-number":["2025JC\u2010YBQN\u2010195"]}],"id":[{"id":"10.13039\/501100017596","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) capture and utilization (CCU), driven by renewable electricity, are pivotal technologies to achieve the mitigation of CO\n                    <jats:sub>2<\/jats:sub>\n                    emissions and further valorization, respectively. Integrating CO\n                    <jats:sub>2<\/jats:sub>\n                    capture with upgrading represents an emerging cutting\u2010edge approach, given that each individual process step incurs significant energetic and economic costs. Herein, hierarchically porous N\u2010doped carbon\u2010supported Ni catalyst (Ni\u2010HP) is architected for KOH\u2010based reactive CO\n                    <jats:sub>2<\/jats:sub>\n                    capture. Benefiting from the hierarchical porous structures with enriched exposure of active sites as well as accelerated mass transfer, this catalyst achieves a high Faradaic efficiency (FE) for CO exceeding 90%. Moreover, this catalyst facilitates industrial syngas production over 60\u00a0h of cyclic operation at \u2212100 mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in alkaline solutions saturated with simulated flue gas containing 20\u00a0vol% CO\n                    <jats:sub>2<\/jats:sub>\n                    . This work not only provides in\u2010depth insight into the origin of the catalytic activity of porous carbon\u2010based catalysts but also offers electrochemical guidance for the rational integration of reactive CO\n                    <jats:sub>2<\/jats:sub>\n                    capture within the broader carbon management community.\n                  <\/jats:p>","DOI":"10.1002\/smll.202509895","type":"journal-article","created":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T08:51:02Z","timestamp":1761382262000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Architecting Hierarchically Porous Electrocatalyst for Direct Liquid Carbon Utilization"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0307-3697","authenticated-orcid":false,"given":"Zhenfang","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Textile Science and Engineering Xi\u2019an Polytechnic University Xi'an Shaanxi 710048 China"},{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yitong","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingfeng","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Fu","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jincheng","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiwen","family":"Zhong","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Li","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Bao","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hai","family":"Yu","sequence":"additional","affiliation":[{"name":"CSIRO Energy 10 Murray Dwyer Circuit  Mayfield West Newcastle NSW 2304 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1042-8700","authenticated-orcid":false,"given":"Tianyi","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Science RMIT University  124 La Trobe St Melbourne VIC 3000 Australia"},{"name":"ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop)  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41558-023-01919-7"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1093\/pnasnexus\/pgae106"},{"key":"e_1_2_7_3_1","first-page":"914","volume":"105","author":"Singh U.","year":"2013","journal-title":"Curr. Sci."},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44582-4"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2020.100942"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EY00287J"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mser.2020.100594"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504515"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110300"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00512C"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coelec.2023.101321"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00048"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.2c00329"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.10.010"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500415"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b00975"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512002"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.216650"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA03237A"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE01448D"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02608A"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcata.2023.100003"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202500223"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903068"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70045"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36688-6"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40970-y"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.26599\/NR.2025.94907297"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202406906"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420001"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c14192"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409099"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218122"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00565"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC06281G"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00699-7"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adw6592"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001869\u20108"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31295-3"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c02058"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie8015895"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404574"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202509895","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,11]],"date-time":"2025-12-11T11:34:52Z","timestamp":1765452892000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202509895"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,25]]},"references-count":42,"journal-issue":{"issue":"49","published-print":{"date-parts":[[2025,12]]}},"alternative-id":["10.1002\/smll.202509895"],"URL":"https:\/\/doi.org\/10.1002\/smll.202509895","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,25]]},"assertion":[{"value":"2025-08-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-10-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e09895"}}