{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,26]],"date-time":"2026-10-26T20:23:48Z","timestamp":1793046228146,"version":"4.5.0"},"reference-count":46,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2025,11,30]],"date-time":"2025-11-30T00:00:00Z","timestamp":1764460800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,30]],"date-time":"2025-11-30T00:00:00Z","timestamp":1764460800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["11727902"],"award-info":[{"award-number":["11727902"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12175098"],"award-info":[{"award-number":["12175098"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20224BAB202032"],"award-info":[{"award-number":["20224BAB202032"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Advanced PVDF\u2010based electrolytes with ceramic\u2010like ion migration behavior, near\u2010separator\u2010level toughness, and excellent oxidation resistance are critical for the practical implementation of solid\u2010state lithium\u2010metal batteries (SSLMBs). However, the superior ion conductivity, robust mechanical property, and wide electrochemical stability usually cannot be achieved simultaneously. Herein, the self\u2010defective silicon (Si) fillers with silicon\/silicon oxide (Si\/SiO\n                    <jats:sub>x<\/jats:sub>\n                    ,0&lt;x\u22642) heterogeneous interfaces are doped into the PVDF matrix to construct the highly conductive and supertough PVDF\u2010based electrolytes. Results reveal that the self\u2010defective Si will spontaneously participate in the Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010solvation state and convert all solvation structure into the Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010[solvent]\n                    <jats:sub>x<\/jats:sub>\n                    \u2010[anion]\n                    <jats:sub>y<\/jats:sub>\n                    (x\u2264y) configuration. The anion\u2010rich Li\n                    <jats:sup>+<\/jats:sup>\n                    coordination environment not only accelerate Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion rate but also promotes the formation of the anion\u2010dominated bilayer interphase. Meanwhile, the strong Lewis acid\u2010base interaction of PVDF\/SiO\n                    <jats:sub>x<\/jats:sub>\n                    interface effectively suppresses phase separation initiated by uneven solvent evaporation. Benefiting from the modified Li\n                    <jats:sup>+<\/jats:sup>\n                    transport environment and phase regulation, the obtained electrolytes exhibit impressive comprehensive properties, including ionic conductivity of 0.44 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , tensile strength of 16.5 Mpa, and voltage window of 5.07\u00a0V. Besides, the Li||Li symmetrical batteries present outstanding cycling under the current density of 0.1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    (&gt;6200\u00a0h), and the LFP||Li batteries exhibit remarkable fast\u2010charging behavior at 10 C with the capacity retention of 82.29%.\n                  <\/jats:p>","DOI":"10.1002\/smll.202509917","type":"journal-article","created":{"date-parts":[[2025,11,30]],"date-time":"2025-11-30T19:28:27Z","timestamp":1764530907000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Highly Conductive and Supertough PVDF\u2010Based Electrolytes with Self\u2010Defective Fillers for Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Kaibo","family":"Fan","sequence":"first","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biao","family":"Wang","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Chen","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Cao","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Chongqing Institute of New Energy Storage Materials and Equipment  Chongqing 401120 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Zhejiang University\u2010Quzhou  Zheda Road 99 Quzhou 324000 China"},{"name":"Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiren","family":"Yuan","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengguang","family":"Hu","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6919-1712","authenticated-orcid":false,"given":"Li","family":"Wang","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Photodetectors School of Physics and Materials Science Nanchang University  Nanchang 330031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,30]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.141"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2085"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00427"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2021.100058"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02401"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.06.025"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2016.07.003"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902029"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201800703"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.05.009"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202308507"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214432"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.06.040"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202100262"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-023-5658-2"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c07482"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401549"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409134"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202010261"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402782"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202304727"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202101537"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01053D"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29118-6"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202203916"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110917"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302711"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-023-01792-x"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202401428"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.146414"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c06924"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2012.08.060"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.2c01903"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311195"},{"key":"e_1_2_7_35_1","volume":"146","author":"Yang K.","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC05464D"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01735"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202314876"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/acf482"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422147"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202500481"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.11.050"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002741"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100046"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307045"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41808-3"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202509917","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202509917","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202509917","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,11]],"date-time":"2026-03-11T15:10:05Z","timestamp":1773241805000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202509917"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,30]]},"references-count":46,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2026,1]]}},"alternative-id":["10.1002\/smll.202509917"],"URL":"https:\/\/doi.org\/10.1002\/smll.202509917","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,30]]},"assertion":[{"value":"2025-08-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e09917"}}