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In this work, a co\u2010solvent strategy assisted blade\u2010coating achieves power factor (PF) breakthrough for P3HT through synergistically modulating the crystallization kinetics and rheological property. By incorporating orthogonal solvent n\u2010hexane (HEX) into host solvent chloroform (CF), the solubility and pre\u2010aggregation of P3HT are effectively modulated to promote nucleation\/crystal\u2010growth during film\u2010forming. Faster P3HT crystal nucleation\/growth and relatively slower co\u2010solvent evaporation endow better\u2010matched crystallization rates, leading to improved molecular assembly. Combined with crystallization\u2010inducing effect of multi\u2010layer blade\u2010coating, significantly enhanced crystallinity is obtained. In addition, solubility parameters variation alters the molecular arrangements into mix\u2010orientation, which is beneficial for doping and alleviating the thermoelectric trade\u2010off. Meanwhile, the viscosity and surface tension of the solution can be accommodated to restrain capillary flow, reinforcing the film uniformity. Consequently, under the optimal co\u2010solvent ratio of CF:HEX = 7:3 (vol\/vol), a conductivity of 605.39 S\u2022cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a new record PF of 204.62 \u00b5W\u2022m\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2022K\n                    <jats:sup>\u22122<\/jats:sup>\n                    are reached for P3HT. The study opens a meaningful path for printing high\u2010performance OTE, revealing the potential for scalable production of OTE architecture.\n                  <\/jats:p>","DOI":"10.1002\/smll.202510495","type":"journal-article","created":{"date-parts":[[2025,10,30]],"date-time":"2025-10-30T08:16:09Z","timestamp":1761812169000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Co\u2010Solvent Strategy Enables High\u2010Performance Printing Organic Thermoelectric via Synergistic Modulation of Crystallinity and Film Homogeneity"],"prefix":"10.1002","volume":"21","author":[{"given":"Xufang","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering\/Film Energy Chemistry for Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang Jiangxi 330031 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