{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T05:57:22Z","timestamp":1788328642139,"version":"build-2803163510"},"reference-count":105,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2025,12,23]],"date-time":"2025-12-23T00:00:00Z","timestamp":1766448000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,23]],"date-time":"2025-12-23T00:00:00Z","timestamp":1766448000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101065"],"award-info":[{"award-number":["22101065"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51972075"],"award-info":[{"award-number":["51972075"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Two\u2010dimensional (2D) heterostructure materials combine the synergistic advantages of their 2D components, such as enhanced specific surface area, increased active sites, and modulated electronic structure, overcoming the limitations of single\u2010component systems and establishing a strong position in electrochemical energy storage. This review summarizes recent advances in 2D MXenes\/metal chalcogenide heterostructures for lithium\u2010ion batteries (LIBs). This manuscript is divided into three sections: MXenes\/metal sulfides, MXenes\/metal selenides, and MXenes\/metal tellurides. The synthetic strategies of heterostructures, including in situ conversion, confined growth, and intercalation self\u2010assembly, are comprehensively introduced, and interfacial coupling mechanisms are mainly discussed. In addition, we summarize representative advances of heterostructures in lithium storage performance and reaction kinetics across various systems. Finally, we highlight key issues in current research, including unclear phase transition mechanisms, environmentally unfriendly and non\u2010scalable preparation methods, and offer suggestions for improvements. And the future prospects of heterostructures in energy storage have also been outlined.<\/jats:p>","DOI":"10.1002\/smll.202510761","type":"journal-article","created":{"date-parts":[[2025,12,23]],"date-time":"2025-12-23T11:46:36Z","timestamp":1766490396000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["The State\u2010of\u2010the\u2010Art Two\u2010Dimensional Heterostructure Engineering on MXenes and Metal Chalcogenides for Boosting Lithium\u2010Ion Storage Properties"],"prefix":"10.1002","volume":"22","author":[{"given":"Miao","family":"Guo","sequence":"first","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianglong","family":"Kong","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zicheng","family":"Fang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xudong","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"},{"name":"College of Material Science and Engineering Heilongjiang Institute of Technology  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenyang","family":"Qiu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junming","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoling","family":"Li","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Qingdao University  Qingdao P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"He","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Piaoping","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5914-5667","authenticated-orcid":false,"given":"Zhiliang","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,23]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn506223h"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b05040"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.04.051"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2024.08.006"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402971"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtphys.2017.07.001"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoso.2024.101299"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2021.101245"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202515680"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910474"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214335"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.98"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-019-0124-1"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05692"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201806314"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202414130"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2023.05.033"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4312-8"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00574"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108682"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139139"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-0657-0"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abf1581"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300580"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.57"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001093"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.158232"},{"key":"e_1_2_7_29_1","article-title":"Ionization\u2010Bombardment Assisted Deposition of MXene\/SiC Heterostructure for Micro\u2010Supercapacitor With Enhanced Sodium Storage","volume":"428","author":"Maoyang X.","year":"2021","journal-title":"Chemical Engineering Journal"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2023.108004"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c16221"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c01959"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c04750"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.150699"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.3c01626"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SE00918D"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12058"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408667"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.6b01091"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00005"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201904271"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.06.010"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.09.142"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201501059"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.143436"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.142100"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.148272"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201404142"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-019-0245-5"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149837"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202308793"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201801568"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202005238"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.89"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300739"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.148266"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202518989"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.261"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b03239"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-021-3439-3"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac9439"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c08436"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.10.080"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100139"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202003437"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202302386"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2023.113592"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201804306"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QI01081A"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710616"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202104286"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108809"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QM00388H"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2023.11.111"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422017"},{"key":"e_1_2_7_76_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2021.117087"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c08770"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.11.135"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202106673"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.4c00025"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00276H"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307269"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c02012"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.148772"},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.04.004"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202304465"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201904118"},{"key":"e_1_2_7_88_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201702061"},{"key":"e_1_2_7_89_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.1c02959"},{"key":"e_1_2_7_90_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307794"},{"key":"e_1_2_7_91_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202206462"},{"key":"e_1_2_7_92_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CE01013H"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202206563"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.148737"},{"key":"e_1_2_7_95_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202405174"},{"key":"e_1_2_7_96_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2019.227559"},{"key":"e_1_2_7_97_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202204671"},{"key":"e_1_2_7_98_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.133463"},{"key":"e_1_2_7_99_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2023.169007"},{"key":"e_1_2_7_100_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.202400384"},{"key":"e_1_2_7_101_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2025.182758"},{"key":"e_1_2_7_102_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202503252"},{"key":"e_1_2_7_103_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.1c02914"},{"key":"e_1_2_7_104_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2021.122605"},{"key":"e_1_2_7_105_1","doi-asserted-by":"publisher","DOI":"10.3866\/PKU.WHXB202303006"},{"key":"e_1_2_7_106_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202424000"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202510761","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202510761","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202510761","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,2]],"date-time":"2026-02-02T08:53:14Z","timestamp":1770022394000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202510761"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,23]]},"references-count":105,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/smll.202510761"],"URL":"https:\/\/doi.org\/10.1002\/smll.202510761","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,23]]},"assertion":[{"value":"2025-09-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-08","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e10761"}}