{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T16:34:34Z","timestamp":1787502874254,"version":"build-2736575974"},"reference-count":66,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2026,2,7]],"date-time":"2026-02-07T00:00:00Z","timestamp":1770422400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,7]],"date-time":"2026-02-07T00:00:00Z","timestamp":1770422400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22425303"],"award-info":[{"award-number":["22425303"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Mesoporous zeolite\u2010anchored atomically dispersed metal (ADM) catalysts are capable of overcoming diffusion limitations, promoting mass transfer, and exposing more active sites. These features make them one of the most ideal heterogeneous catalysts. However, introducing both mesoporosity and ADM species into zeolite structures while avoiding metal clustering remains a significant challenge. Herein, we report the hierarchical\n                    <jats:bold>MFI<\/jats:bold>\n                    zeolite encapsulated atomically dispersed nickel species using a ligand\u2010protected in situ synthesis strategy with a tri\u2010functional template. This template incorporates quaternary ammonium hydrophilic head groups linked to central metal\u2010coordinated porphyrins by alkyl chains, which guide the formation of mesoporous\n                    <jats:bold>MFI<\/jats:bold>\n                    zeolite structure while simultaneously suppressing nickel clustering. The resulting catalyst exhibits a hierarchical architecture comprising\n                    <jats:bold>MFI<\/jats:bold>\n                    nanosheets with enhanced 90\u00b0 rotational intergrowth, and the dispersed Ni sites are evenly distributed within the zeolite framework. The catalyst exhibited a high activity and efficient utilization of Ni in probing CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation reaction. The use of functionalized metal\u2010coordinated porphyrins as a structure\u2010directing agent to generate zeolite\u2010supported metal catalysts is transferable, which opens new possibilities for controlling zeolite architecture.\n                  <\/jats:p>","DOI":"10.1002\/smll.202510776","type":"journal-article","created":{"date-parts":[[2026,2,7]],"date-time":"2026-02-07T16:49:08Z","timestamp":1770482948000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis of Atomically Dispersed Nickel Confined in Hierarchical MFI Zeolite"],"prefix":"10.1002","volume":"22","author":[{"given":"Quanzheng","family":"Deng","sequence":"first","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai P. R. China"},{"name":"Department of Physics, State Key Laboratory of Quantum Functional Materials Guangdong Basic Research Center of Excellence for Quantum Science, Guangdong Provincial Key Laboratory of Advanced Thermoelectric Materials and Device Physics, and Shenzhen Key Laboratory of Thermoelectric Materials, Southern University of Science and Technology  Shenzhen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Neng","family":"Gong","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6119-4895","authenticated-orcid":false,"given":"Lu","family":"Han","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai P. R. 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