{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T00:17:29Z","timestamp":1789777049133,"version":"4.0.1"},"reference-count":54,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2025,11,19]],"date-time":"2025-11-19T00:00:00Z","timestamp":1763510400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Porous materials are of critical importance in applications such as catalysis and separation due to their tailorable pore architectures. Research now encompasses metal\u2010organic frameworks (MOFs), with growing attention to their dynamic structural flexibility in response to external stimuli. While thermal, pressure, and light stimuli provide means of control, their implementation faces limitations such as poor heat transfer efficiency and material compatibility constraints. Comparatively, electric fields (EFs) offer a promising alternative stimulus, circumventing mass\/heat transfer barriers and thus enhancing applicability. This study investigates the structural response of Materials of Institute Lavoisier (MIL)Materials of Institute Lavoisier\u2010series MOFs to EFs.\n                    <jats:italic>Ex situ<\/jats:italic>\n                    and\n                    <jats:italic>in situ<\/jats:italic>\n                    X\u2010ray analyses reveal that EFs induce an unexpected framework contraction in MIL\u201053 (Cr), distinct from its conventional large\u2010pore\/narrow\u2010pore transitions triggered by other stimuli. This contraction increases pore charge density and significantly enhances CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and selectivity. Similar responses observed across several MIL MOFs (MIL\u201053 (Fe), MIL\u201047 (V), and MIL\u2010101 (Cr)) indicate a universal structural adaptability to EFs. These findings elucidate mechanisms of EF\u2010induced structural changes in MIL\u2010series MOFs and their direct impact on gas adsorption properties, particularly for CO\n                    <jats:sub>2<\/jats:sub>\n                    capture. It provides a pathway for precise,\n                    <jats:italic>in situ<\/jats:italic>\n                    control of pore structure and functionality using EFs, opening new prospects for designing advanced adsorbents applying in separation and catalysis.\n                  <\/jats:p>","DOI":"10.1002\/smll.202511689","type":"journal-article","created":{"date-parts":[[2025,11,19]],"date-time":"2025-11-19T19:15:39Z","timestamp":1763579739000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Electric\u2010Field Induced Unconventional Flexibility of MIL\u2010Series MOFs and Its Application in Carbon Capture"],"prefix":"10.1002","volume":"22","author":[{"given":"Xiangwei","family":"Huang","sequence":"first","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7523-1928","authenticated-orcid":false,"given":"Kaifei","family":"Chen","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"Photon Science Research Center for Carbon Dioxide Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingbo","family":"Wang","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6074-3509","authenticated-orcid":false,"given":"Deng","family":"Hu","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"Photon Science Research Center for Carbon Dioxide Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lina","family":"Zhang","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion 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Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wei","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"Photon Science Research Center for Carbon Dioxide Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"},{"name":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nannan","family":"Sun","sequence":"additional","affiliation":[{"name":"Research Center of Low\u2010Carbon Conversion Science and Engineering Shanghai Advanced 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