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In this work, fluorinated UIO\u201066 (UIO\u201066\u2010F) nanoparticles are synthesized through molecular design and employed to construct a superhydrophobic hierarchical coating via an optimized multilayer spraying process with epoxy resin (EP). The UIO\u201066\u2010F\/EP coating exhibits excellent adhesion and substrate universality on various surfaces, including Q235 steel and ceramics. Moreover, the resulting coating demonstrates exceptional corrosion resistance, remarkable anti\u2010icing capability, significant self\u2010cleaning property, and robust mechanical strength. The molecular dynamics simulations and surface energy theory analyses reveal the synergistic protection mechanism of the MOF\u2010based coating from molecular\u2010scale interactions, interfacial energy modulation, and topological structure. Following a 60\u2010day immersion in 3.5 wt.% NaCl solution, the impedance magnitude of the coating at a frequency of 0.01\u00a0Hz remains approximately seven orders of magnitude higher than that of uncoated Q235 steel. The protective mechanism is systematically elucidated from dual perspectives of low surface energy characteristics and micro\/nanoscale hierarchical structure based on molecular dynamics simulations and surface energy theory analysis. The findings advance the understanding of the formation mechanisms of superhydrophobic surfaces and provide a theoretical foundation for developing novel superhydrophobic protective coatings.<\/jats:p>","DOI":"10.1002\/smll.202511751","type":"journal-article","created":{"date-parts":[[2026,1,17]],"date-time":"2026-01-17T09:50:56Z","timestamp":1768643456000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Superhydrophobic Coatings with Perfluorinated Metal\u2013Organic Frameworks for Enhanced Corrosion Resistance"],"prefix":"10.1002","volume":"22","author":[{"given":"Tianxiang","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology Tianjin University  Tianjin P. R. China"},{"name":"Tianjin Key Laboratory of Membrane Science and Desalination Technology State Key Laboratory of Chemical Engineering and Low\u2010Carbon Technology (Tianjin University)  Tianjin P. R. 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