{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T17:19:30Z","timestamp":1792516770894,"version":"4.5.0"},"reference-count":52,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T00:00:00Z","timestamp":1773964800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T00:00:00Z","timestamp":1773964800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    We developed a novel hybrid gas sensor by integrating zeolitic imidazolate framework\u201067 (ZIF\u201067) onto platinum diselenide (PtSe\n                    <jats:sub>2<\/jats:sub>\n                    ) layered thin films, synthesized via a plasma\u2010assisted selenization process. This approach addresses the critical challenge of scalability in 2D material\u2010based sensors. By leveraging the distinct adsorption energies of gas molecules at the metal centers in ZIF\u201067, the sensors exhibited a significantly enhanced H\n                    <jats:sub>2<\/jats:sub>\n                    S response of up to 163% at 10 ppm and remarkable selectivity against NH\n                    <jats:sub>3<\/jats:sub>\n                    , achieving a response ratio (S\n                    <jats:sub>H2S<\/jats:sub>\n                    \/S\n                    <jats:sub>NH3<\/jats:sub>\n                    ) of 10.9. We calculated a theoretical limit of detection (LOD) of 12 ppb, demonstrating suitability for trace\u2010level environmental monitoring. Long\u2010term stability tests over a month demonstrated the superior stability of ZIF\u201067@PtSe\n                    <jats:sub>2<\/jats:sub>\n                    layered films compared to pristine PtSe\n                    <jats:sub>2<\/jats:sub>\n                    , while maintaining robust performance under high\u2010temperature and high\u2010humidity conditions. Density functional theory (DFT) calculations revealed that ZIF\u201067 acts as a molecular sieve, selectively capturing H\n                    <jats:sub>2<\/jats:sub>\n                    S while hindering access to NH\n                    <jats:sub>3<\/jats:sub>\n                    , elucidating the underlying mechanism for the enhanced selectivity. Crucially, we successfully demonstrated the fabrication of a 4\u2010inch wafer\u2010scale device featuring a highly uniform ZIF\u201067@PtSe\n                    <jats:sub>2<\/jats:sub>\n                    layered thin film that exhibited excellent gas\u2010sensing performance. These results validate the feasibility and potential for large\u2010scale, high\u2010volume manufacturing of ZIF\u201067@PtSe\n                    <jats:sub>2<\/jats:sub>\n                    sensors, bridging the gap between laboratory\u2010scale devices and commercial applications.\n                  <\/jats:p>","DOI":"10.1002\/smll.202511890","type":"journal-article","created":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T18:14:51Z","timestamp":1774030491000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Enhanced Selectivity of Hydrogen Sulfide Gas by Hybrid Zeolitic Imidazolate Framework\u201067\/2D Platinum Diselenide\u2010Based Sensors Toward Wafer\u2010Scale Production"],"prefix":"10.1002","volume":"22","author":[{"given":"Tzu\u2010Wen","family":"Kuo","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul Albert L.","family":"Sino","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hai\u2010Feng","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u2010Hao","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruei\u2010Hong","family":"Cyu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Chieh","family":"Hsu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Heng","family":"Hong","sequence":"additional","affiliation":[{"name":"Department of Photonics College of Electrical and Computer Engineering National Yang Ming Chiao Tung University  Hsinchu Taiwan"},{"name":"Semiconductor Research Center Hon Hai Research Institute  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng\u2010Chuan","family":"Chuang","sequence":"additional","affiliation":[{"name":"Department of Physics National Sun Yat\u2010Sen University  Kaohsiung Taiwan"},{"name":"Physics Division National Center for Theoretical Sciences  Taipei Taiwan"},{"name":"Center for Theoretical and Computational Physics National Sun Yat\u2010sen University  Kaohsiung Taiwan"},{"name":"Department of Physics National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao\u2010Chung","family":"Kuo","sequence":"additional","affiliation":[{"name":"Department of Photonics College of Electrical and Computer Engineering National Yang Ming Chiao Tung University  Hsinchu Taiwan"},{"name":"Semiconductor Research Center Hon Hai Research Institute  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ho\u2010Hsiu","family":"Chou","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Tsing Hua University  Hsinchu Taiwan"},{"name":"College of Semiconductor Research National Tsing Hua University  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0155-9987","authenticated-orcid":false,"given":"Yu\u2010Lun","family":"Chueh","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, National Tsing Hua University  Hsinchu Taiwan"},{"name":"Department of Physics National Sun Yat\u2010Sen University  Kaohsiung Taiwan"},{"name":"College of Semiconductor Research National Tsing Hua University  Hsinchu Taiwan"},{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,20]]},"reference":[{"key":"e_1_2_9_2_1","first-page":"1072","article-title":"Assessment of Volatile Organic Compound and Hazardous Air Pollutant Emissions from Oil and Natural Gas well Pads using Mobile Remote and on\u2010site Direct Measurements","volume":"65","author":"Brantley H. 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