{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T21:23:22Z","timestamp":1790803402214,"version":"4.1.0"},"reference-count":91,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>As a higher homologue of rylene with six fused benzene rings, terrylene exhibits distinct optoelectronic properties compared to its lower analogues, naphthalene, and perylene. In 1948, E. Clar reported the synthesis of terrylene for the first time, marking the beginning of higher rylene chemistry. Numerous synthetic routes have led to the establishment of a diverse array of terrylene\u2010based chromophores in the literature so far. The extensive \u03c0\u2010conjugated surface of terrylene derivatives promotes strong intermolecular \u03c0\u2010\u03c0 stacking interactions. Synthesis challenges and poor solubilities hindered the progress of core terrylene molecules and their analogues, such as aza\u2010terrylenes and benzo\u2010fused terrylenes, in multiple application domains. However, the field gained significant momentum with M\u00fcllen and coworkers' pioneering report of terrylene tetracarboxydiimide (TDI) in 1997. Following the initial report, the chemistry of TDI and its derivatives has been explored in multiple domains due to their high solubility, optimal bandgap, and unique optoelectronic and redox properties. Due to the presence of a large \u03c0\u2010surface, terrylene derivatives often exert strong intermolecular \u03c0\u2013\u03c0 stacking interactions. Facilitating these unique properties, TDI and its derivatives were explored in bulk heterojunction organic solar cells, organic field\u2010effect transistors, photochromic switching, single\u2010molecule photophysics, bioimaging, and supramolecular chemistry. In this review article, we focus on the synthesis of various terrylenes, TDIs, and their derivatives, as well as their applications in multiple domains.<\/jats:p>","DOI":"10.1002\/smll.202511895","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T10:57:15Z","timestamp":1767869835000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Terrylene: Synthesis, Modifications, and Multifaceted Applications"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-4796-9300","authenticated-orcid":false,"given":"Chitrak","family":"Ghosh","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9587-977X","authenticated-orcid":false,"given":"Suman 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