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To address these challenges, we develop a 3D resilient and conductive binding network through the cross\u2010linking of sodium alginate (SA) with MXene Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    , thereby enhancing the mechanical stability and charge transfer efficiency within silicon anodes. The SA@Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    binding network effectively reduces the growth rate of electrode thickness from 100.6% to 46.6%, mitigating electrolyte decomposition and excessive SEI growth during cycling, and contributing to the formation of a stable LiF\u2010rich SEI layer on silicon surfaces. Enhanced mechanical strength and electron conduction provided by the 3D interconnected conductive network facilitate a high reversible capacity of 1247.01\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 300 cycles and excellent rate capability of 778.12\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a current density of 2\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , even with a silicon content as high 80% by weight. By simultaneously reinforcing the mechanical stability and electron transport pathways, this work paves the way for innovative design of high\u2010capacity negative electrodes.\n                  <\/jats:p>","DOI":"10.1002\/smll.202511954","type":"journal-article","created":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T12:24:04Z","timestamp":1768825444000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Encapsulating Silicon Nanoparticles Within a 3D Interconnected Ultra\u2010Conductive Sodium Alginate@Ti\n                    <sub>3<\/sub>\n                    C\n                    <sub>2<\/sub>\n                    T\n                    <sub>x<\/sub>\n                    Network for Robust and High\u2010Capacity Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Li","family":"Dai","sequence":"first","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zimo","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Metallurgy and Environment Central South University  Changsha Hunan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuqi","family":"Lin","sequence":"additional","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juncheng","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute for Sustainable Transformation 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