{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T13:50:47Z","timestamp":1791985847047,"version":"4.4.0"},"reference-count":53,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T00:00:00Z","timestamp":1770681600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T00:00:00Z","timestamp":1770681600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0211200"],"award-info":[{"award-number":["2024YFE0211200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) to valuable liquid fuels offers a promising solution for global warming. The challenges of low CO\n                    <jats:sub>2<\/jats:sub>\n                    delivery and poor product selectivity hinder the practical application of CO\n                    <jats:sub>2<\/jats:sub>\n                    RR technology. This study proposes electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010formic acid (HCOOH) conversion using a cypress\u2010like carbonic anhydrase\/antimony\u2010decorated bismuth (CA\/Sb\u2010decorated Bi) biohybrid. The carbonic anhydrase (CA) as CO\n                    <jats:sub>2<\/jats:sub>\n                    shuttle can enrich CO\n                    <jats:sub>2<\/jats:sub>\n                    concentration on the electrode surface, accelerating the CO\n                    <jats:sub>2<\/jats:sub>\n                    hydration kinetics and reaction rate. Density functional theory (DFT) calculations indicate that the introduction of Sb can alter the adsorption energy of H* and HCOO*, which is beneficial for CO\n                    <jats:sub>2<\/jats:sub>\n                    RR to form HCOOH. Besides, CA\/Sb\u2010decorated Bi biohybrid can suppress competitive hydrogen evolution reactions (HER). Consequently, the CA\/Sb\u2010decorated Bi biohybrid achieves the Faradaic efficiency of 93.41% and 100% selectivity for HCOOH at \u22121.3\u00a0V. This work demonstrates the application potential of enzyme modification and metal decorating in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR for the development of sustainable energy.\n                  <\/jats:p>","DOI":"10.1002\/smll.202512077","type":"journal-article","created":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T14:49:06Z","timestamp":1770734946000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["High\u2010Performance Electrocatalytic Carbon Dioxide Reduction to Formic Acid on Cypress\u2010Like Enzyme\u2010Antimony\u2010Bismuth Biohybrid"],"prefix":"10.1002","volume":"22","author":[{"given":"Zhe","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Macromolecular Science of Shaanxi Province School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohui","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Macromolecular Science of Shaanxi Province School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueqing","family":"Gao","sequence":"additional","affiliation":[{"name":"College of Chemical and Pharmaceutical Engineering Hebei University of Science and Technology  Shijiazhuang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) Shaanxi Normal University  Xi'an P. R. 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