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In this study, a series of ZnAlOx\u2010based catalysts are synthesized and employed for the catalytic hydrolysis of COS. Copper oxide (CuO) and zirconium oxide (ZrO\n                    <jats:sub>2<\/jats:sub>\n                    ) are the predominant catalytic active components. Adsorbed oxygen and hydroxyl oxygen on ZnAlOx are the primary oxygen species involved in the COS hydrolysis process. Oxygen vacancies are identified as a critical factor in the COS catalytic hydrolysis process. The synergistic effect of Cu and Zr can regulate the excessive oxidation of hydrogen sulfide (H\n                    <jats:sub>2<\/jats:sub>\n                    S) and further augment the number of oxygen vacancies on the catalyst surface. The \u2500OH functional group exhibits a higher degree of reactivity compared to the C\u2500H functional group. The synergistic effect of Cu and Zr can provide sufficient hydroxyl groups for the COS hydrolysis reaction and effectively control the secondary over\u2010oxidation of H\n                    <jats:sub>2<\/jats:sub>\n                    S. Oxygen vacancies augment the adsorption of COS and H\n                    <jats:sub>2<\/jats:sub>\n                    O, and is advantageous for the hydrolysis reaction of COS and H\n                    <jats:sub>2<\/jats:sub>\n                    O. The collective effect of CuO, ZrO\n                    <jats:sub>2<\/jats:sub>\n                    , and oxygen vacancies is a reduction in the reaction energy barrier during the hydrolysis of COS.\n                  <\/jats:p>","DOI":"10.1002\/smll.202512487","type":"journal-article","created":{"date-parts":[[2025,11,26]],"date-time":"2025-11-26T11:47:56Z","timestamp":1764157676000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Regulating Oxygen Vacancies and Desulfurization Product Selectivity through Cu\u2010Zr Bimetallic Synergy to Enhance Low\u2010Temperature Catalytic Hydrolysis of Carbonyl Sulfide (COS)"],"prefix":"10.1002","volume":"22","author":[{"given":"Xin","family":"Song","sequence":"first","affiliation":[{"name":"Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering  Yantai 264006 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Laboratory for Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4595-193X","authenticated-orcid":false,"given":"Zhicheng","family":"Tang","sequence":"additional","affiliation":[{"name":"Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering  Yantai 264006 China"},{"name":"National Engineering Research Center for Fine Petrochemical Intermediates State Key Laboratory for Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 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