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Herein, we design an electrode\/electrolyte interface coupled with W\n                    <jats:sub>2<\/jats:sub>\n                    N nanoparticles and single\u2010atom W (SA\u2010W) on ultrathin carbon nanosheets for improving the conversion reaction kinetics of Li\u2013S batteries from the perspective of accelerating the desolvation of lithium polysulfides (LiPSs). The desolvation kinetics near the electrode\/electrolyte interface are enhanced by the excoriation\u2010type effect of SA\u2010W, first exfoliating the solvation sheath of LiPSs through d\u20102p hybridization, and then by W\n                    <jats:sub>2<\/jats:sub>\n                    N nanoparticles adsorbing LiPSs and catalyzing their reduction reaction. Structurally, these carbon nanosheets are self\u2010assembled into hollow microspheres, which reinforce the spatial confinement effect and accommodate the volume change during lithiation\/delithiation under high sulfur loading. Such optimized catalyst\u2010reactant\/\u2010solvent interactions have elicited superb rate capability (with reversible capability of 702 mAh\/g at 5C) and remarkable cycling stability (with capacity degradation rate as small as 0.05% per cycle at 1C over 600 cycles). Benefiting from the rapid desolvation process of LiPSs, a high areal capacity of 13.5 mAh\/cm\n                    <jats:sup>2<\/jats:sup>\n                    can be achieved even under high sulfur loading (11.4\u00a0mg\/cm\n                    <jats:sup>2<\/jats:sup>\n                    ) and low electrolyte\/sulfur ratio (5 \u00b5L\/mg). The proposed catalyst\/solvent interface engineering has the potential to inspire sustainable liquid\u2010solid interconversion electrochemical energy storage.\n                  <\/jats:p>","DOI":"10.1002\/smll.202512813","type":"journal-article","created":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T08:55:07Z","timestamp":1768380907000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Excoriation\u2010Type Catalyst\u2010Solvent Interface with Dual Active Sites to Enhance Polysulfide Desolvation Kinetics for Lean\u2010Electrolyte Lithium\u2013Sulfur Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Xuejun","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China"},{"name":"CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhan","family":"Mei","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering North Carolina State University  Raleigh NC USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weichao","family":"Bao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingping","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Electrochemical Energy Storage Helmholtz\u2010Zentrum Berlin f\u00fcr Materialien und Energie Berlin Germany"},{"name":"Chongqing Institute of Green and Intelligent Technology Chinese Academy of Sciences  Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangfang","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5587-8617","authenticated-orcid":false,"given":"Chilin","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China"},{"name":"CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,14]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010023\u201006326\u20108"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202306933"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010023\u201001137\u2010y"},{"key":"e_1_2_8_5_1","first-page":"545","article-title":"kinetic Promoters For Sulfur Cathodes In Lithium\u2013Sulfur Batteries","volume":"57","author":"Zhao M.","year":"2024","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202094"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2460"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2019.01.005"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010024\u201001614\u20104"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104053"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.06.009"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b09231"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.11.037"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c09919"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04472"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137294"},{"key":"e_1_2_8_17_1","article-title":"Scissor g\u2010C3N4 for High\u2010Density Loading Of Catalyst Domains In Mesoporous Thin\u2010Layer Conductive Network For Durable Li\u2010S Batteries","volume":"3","author":"Lai C. 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