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In this study, we propose a facile low\u2010cost hydrogen chloride\u2013assisted gelation strategy to fabricate a free\u2010standing, coral\u2010like MXene\/carbon nanotube (CNT) foam cathode at ambient temperature and pressure. This self\u2010assembly process eliminates the need for high\u2010temperature or high\u2010pressure conditions, making it suitable for large\u2010scale production. The hierarchical porous structure provides multiscale confinement and continuous ion\/electron pathways, enhancing both polysulfide confinement and ion transport. The chloride\u2010induced surface modification of MXene promotes a transition from 2D film\u2010like to 3D particulate sulfur deposition, improving redox kinetics and mitigating electrode passivation. The resulting cathode delivers excellent electrochemical performance, achieving 775 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 4 C with 74.5% retention after 500 cycles and maintaining 827 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.5 C under practical conditions (high sulfur loading, lean electrolyte), with a low decay rate of 0.11% per cycle. This work demonstrates the potential of self\u2010assembly and surface chemistry modulation in enhancing Li\u2013S battery performance without the need for complex or energy\u2010intensive synthesis.\n                  <\/jats:p>","DOI":"10.1002\/smll.202513358","type":"journal-article","created":{"date-parts":[[2025,12,31]],"date-time":"2025-12-31T05:22:01Z","timestamp":1767158521000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Facile Self\u2010Assembly of Coral\u2010Like MXene\u2010Sulfur Free\u2010Standing Electrodes for Efficient Polysulfide Confinement and Accelerated Redox Kinetics"],"prefix":"10.1002","volume":"22","author":[{"given":"Yukun","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Tongji University  Shanghai P. R. 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