{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,16]],"date-time":"2026-07-16T22:40:06Z","timestamp":1784241606385,"version":"3.55.0"},"reference-count":41,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1507400"],"award-info":[{"award-number":["2023YFA1507400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1507403"],"award-info":[{"award-number":["2023YFA1507403"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22090031"],"award-info":[{"award-number":["22090031"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22288102"],"award-info":[{"award-number":["22288102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["buctrc202527"],"award-info":[{"award-number":["buctrc202527"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalysis offers a sustainable pathway for upcycling polyethylene terephthalate (PET) waste. However, existing approaches often rely on high precious\u2010metal loadings and suffer rapid deactivation, limiting scalability. Herein, we report a full\u2010molecule valorization strategy for PET hydrolysates. PET\u2010derived benzene\u20101,4\u2010dicarboxylate (BDC) is upcycled into a bifunctional Pt\/Ni\u2010BDC catalyst, thereby reducing noble\u2010metal loading while achieving a remarkable current density of 378.8\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for ethylene glycol (EG) oxidation at 1.0\u00a0V vs. RHE with 90% glycolic acid (GA) selectivity. Mechanistic studies reveal that the Ni\u2010BDC framework enhances EG adsorption, thereby boosting performance. Additionally, the catalyst demonstrates excellent hydrogen evolution reaction activity, requiring only 39.6\u00a0mV to reach 50\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , outperforming commercial Pt\/C. As a proof\u2010of\u2010concept, the catalyst was employed as the bifunctional electrode in a membrane\u2010free electrolyzer, enabling continuous electrochemical hydrogen production coupled with EG oxidation at ampere\u2010level current. The resulting GA was subsequently polymerized into biodegradable polyglycolic acid (PGA). Moreover, we developed an open\u2010loop flow battery integrating Pt\/Ni\u2010BDC, which enables simultaneous electricity generation and GA production, delivering a discharge capacity of 3.53\u00a0Ah L\n                    <jats:sup>\u22121<\/jats:sup>\n                    and an energy efficiency of 81%. By achieving full\u2010molecule valorization of PET hydrolysates, this work delivers a multifunctional platform for closed\u2010loop plastic valorization and green\u2010energy generation.\n                  <\/jats:p>","DOI":"10.1002\/smll.202513474","type":"journal-article","created":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T12:28:12Z","timestamp":1768912092000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electrocatalytic Valorization of PET Hydrolysates Into High\u2010Value Chemicals Coupled With Renewable Energy Generation"],"prefix":"10.1002","volume":"22","author":[{"given":"Yifan","family":"Yan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanguo","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiyuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Quzhou Institute For Innovation in Resource Chemical Engineering  Quzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Fu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yizhong","family":"Zou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucong","family":"Miao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dawei","family":"Gao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiwei","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yayue","family":"Dai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhua","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Quzhou Institute For Innovation in Resource Chemical Engineering  Quzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6461-623X","authenticated-orcid":false,"given":"Mingfei","family":"Shao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Quzhou Institute For Innovation in Resource Chemical Engineering  Quzhou 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