{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T05:01:51Z","timestamp":1783400511255,"version":"3.54.6"},"reference-count":70,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T00:00:00Z","timestamp":1767830400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    SPEs have gained significant attention in lithium metal batteries for enhanced safety. However, low ionic conductivity and dendrite formation limit the performance. To address these limitations, a novel composite\u2010type SPE was developed by incorporating phytic acid(PA)\u2010functionalized ZIF\u201067 (ZIFP) into \uff08N\u2010Methyl\u20102\u2010Pyrrolidone\uff09NMP\u2010modified \uff08Poly(vinylidenefluoride\u2010co\u2010vinylchloride\u2010co\u2010vinylidenefluoride)_PVDF\u2010HFP Solid polmer electrolyte(SPE). The 2D HETCOR Nuclear magnetic resonance(NMR)\u00a0reveals that the oxygen\u2010rich functional groups of PA not only improve the filler\u2010polymer interfacial affinity for the uniform dispersion of ZIFP, but also promote the formation of a hydrogen\u2010bond network with the PVDF\u2010HFP chains, resulting in a consistent, high Li\n                    <jats:sup>+<\/jats:sup>\n                    flux. Moreover, the inherent hierarchical sites and anionic confinement effect of ZIFP, in combination with the solvent\u2010regulating role of NMP, collaboratively enhance the lithium salt dissociation and enable selective Li\n                    <jats:sup>+<\/jats:sup>\n                    transport. Conclusively, the PTN\u2010ZIFP SPE achieves superior ionic conductivity (8.4 \u00d7 10\n                    <jats:sup>\u22124<\/jats:sup>\n                    S cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), outstanding critical current density (1.7\u00a0mA cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ) and stable SEI suppressing lithium dendrites (Li||Li cells exhibit stable cycling for over 2000\u00a0h at the current density of 0.1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ). The assembled LFP|PTN\u2010ZIFP|Li cell possesses capacity retentional that achieves 93.2% at 0.5\u00a0C after 1000 cycles. This work presents an innovative approach for designing safe and durable solid\u2010state lithium metal batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.202513488","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T11:18:02Z","timestamp":1767871082000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["MOF in Polymer Electrolytes Raising Ion Transport for Breakthrough Lithium Metal Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Xi","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering China University of Geosciences (Beijing)  Beijing P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Lv","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering National University of Singapore  Singapore Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li\u2010ming","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering China University of Geosciences (Beijing)  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering China University of Geosciences (Beijing)  Beijing P. R. 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