{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T17:05:47Z","timestamp":1784307947928,"version":"3.55.0"},"reference-count":45,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T00:00:00Z","timestamp":1768348800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T00:00:00Z","timestamp":1768348800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of efficient electrocatalysts for sustainable hydrogen production integrated with CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization is crucial for carbon\u2010neutral energy cycles. The metal\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    system exploits dissolution\u2010derived CO\n                    <jats:sub>2<\/jats:sub>\n                    under neutral conditions to co\u2010generate hydrogen and carbonate, offering a promising route for indirect CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization. Here, this study develops a hierarchical Ni foam\u2010supported Pt\u2010Mo ionic cluster electrocatalyst (NiPtMoO\n                    <jats:sub>x<\/jats:sub>\n                    ) for efficient hydrogen evolution reaction (HER) with integrated CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization. The catalyst achieves an exceptionally low overpotential of 142\u00a0mV at \u2212100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in KHCO\n                    <jats:sub>3<\/jats:sub>\n                    electrolyte, significantly surpassing commercial Pt\/C (225\u00a0mV), while maintaining stability for over 1000\u00a0h. DFT calculations indicate that Mo doping optimizes the\n                    <jats:italic>d<\/jats:italic>\n                    \u2010band center of Pt, thereby enhancing HER kinetics. When integrated into a Zn\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    system, it co\u2010produces KHCO\n                    <jats:sub>3<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    with a power density of 71.3\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , exceeding Pt\/C by 37.6%. A scaled\u2010up Zn\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    system with 100\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    NiPtMoO\n                    <jats:sub>x<\/jats:sub>\n                    electrode delivers 1.27\u00a0W peak power and stable 100 h operation at 1\u00a0A. This work offers a synergistic approach for concurrent CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization and energy\u2010efficient H\n                    <jats:sub>2<\/jats:sub>\n                    production, advancing integrated carbon mitigation and energy storage.\n                  <\/jats:p>","DOI":"10.1002\/smll.202513752","type":"journal-article","created":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T09:39:20Z","timestamp":1768383560000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["An Integrated Zn\u2013CO\n                    <sub>2<\/sub>\n                    System With Ultralow Overpotential for Sustainable Hydrogen Production and Carbon Cycling"],"prefix":"10.1002","volume":"22","author":[{"given":"Yueze","family":"Li","sequence":"first","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yibei","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biao","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongchao","family":"Qiu","sequence":"additional","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunling","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2072-1991","authenticated-orcid":false,"given":"Bingbing","family":"Niu","sequence":"additional","affiliation":[{"name":"School of Science University of Science and Technology Liaoning  Anshan P. R. China"},{"name":"Key Laboratory of Interfacial Physics and Technology Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Feng","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen P. R. 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