{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T06:07:52Z","timestamp":1783836472310,"version":"3.55.0"},"reference-count":62,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2026,1,29]],"date-time":"2026-01-29T00:00:00Z","timestamp":1769644800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,29]],"date-time":"2026-01-29T00:00:00Z","timestamp":1769644800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20232ACB204010"],"award-info":[{"award-number":["20232ACB204010"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    2D layered transition metal thiophosphites (MPS\n                    <jats:sub>3<\/jats:sub>\n                    ) are promising high\u2010capacity anodes for sodium\u2010ion batteries (SIBs) but are plagued by poor conductivity and severe volume changes. To address these challenges, we report a corn\u2010like multi\u2010MPS\n                    <jats:sub>3<\/jats:sub>\n                    heterostructure engineered via a sophisticated MOF\u2010on\u2010MOF templating strategy. This unique architecture, comprising a FePS\n                    <jats:sub>3<\/jats:sub>\n                    \/ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    heterojunction and a conformal N\u2010doped carbon (NC) coating, establishes an interfacial field and spatial confinement synergy that facilitates rapid ion\/electron transport and ensures exceptional structural integrity. The designed FePS\n                    <jats:sub>3<\/jats:sub>\n                    \u2010ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    \u2010C@NC anode delivers remarkable sodium storage performance: a high initial discharge capacity of 1294.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and long cycling stability with 87.6% capacity retention after 1200 cycles at 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\u00a0Such superior performance is attributed to: (i) the elastic carbon coating, which effectively buffers mechanical strain and preserves structural stability; and (ii) the heterointerfacial synergy, which enhances charge carrier mobility and reaction kinetics. Ex situ characterizations unravel a multi\u2010mechanistic sodium storage process, accounting for the high capacity. Density functional theory (DFT) calculations confirm that the built\u2010in electric field at the FePS\n                    <jats:sub>3<\/jats:sub>\n                    \/ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    interface optimizes Na\n                    <jats:sup>+<\/jats:sup>\n                    adsorption energy and interfacial charge transfer. This study provides a generalizable design paradigm for high\u2010performance anodes through the rational integration of architectural control and interfacial engineering.\n                  <\/jats:p>","DOI":"10.1002\/smll.202513825","type":"journal-article","created":{"date-parts":[[2026,1,29]],"date-time":"2026-01-29T08:16:50Z","timestamp":1769674610000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Heterointerfacial and Architectural Engineering in MOF\u2010Templated Corn\u2010Like FePS\n                    <sub>3<\/sub>\n                    \u2010ZnPS\n                    <sub>3<\/sub>\n                    \u2010C@NC Anode for Durable Sodium Storage"],"prefix":"10.1002","volume":"22","author":[{"given":"Xilin","family":"Wang","sequence":"first","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang 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