{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T10:13:14Z","timestamp":1783937594393,"version":"3.55.0"},"reference-count":39,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T00:00:00Z","timestamp":1773878400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T00:00:00Z","timestamp":1773878400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100018617","name":"Liaoning Revitalization Talents Program","doi-asserted-by":"publisher","award":["XLYC2403019"],"award-info":[{"award-number":["XLYC2403019"]}],"id":[{"id":"10.13039\/501100018617","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M750308"],"award-info":[{"award-number":["2024M750308"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22502022"],"award-info":[{"award-number":["22502022"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>The adsorption configuration regulation of molecules on the metal site is crucial in the targeted conversion of specific functional groups. Herein, we propose a strategy to adjust the adsorption configuration of substrate molecules by switching the channel screening effect of MOF, thereby achieving the targeted regulation of the selective hydrogenation pathway of furfural. Specifically, two Pd\u2010containing MOF with different Pd locations were fabricated, in which Pd nanoclusters are confined within the MOF cavities and Pd nanoparticles grow on the MOF external surface. Since furfural must pass through the MOF to contact with the Pd cluster, thus forcing furfural to present a linear adsorption configuration and selectively activates the C\u2550O bonds. In contrast, surface Pd particles shield the channel effect, allowing furfural to adopt a thermodynamically stable planar adsorption mode, resulting in hydrogenation of both C\u2550O and C\u2550C bonds. This work provides insights into the adjustment of substrate adsorption configurations, and the proposed channel screening adsorption mechanism also provides ideas for designing catalysts with complex molecular orientation conversion.<\/jats:p>","DOI":"10.1002\/smll.202514192","type":"journal-article","created":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T09:30:03Z","timestamp":1773912603000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Switching the Channel Screening Effect of Metal\u2013Organic Frameworks to Control the Selectivity of Furfural Hydrogenation"],"prefix":"10.1002","volume":"22","author":[{"given":"Yuanxia","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwei","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongru","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianshuo","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9072-8331","authenticated-orcid":false,"given":"Min","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,19]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01838"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.166882"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4GC01983K"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC04440K"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02171"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02276"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c00333"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c09234"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202417584"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c05078"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202521821"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b00238"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2023.03.009"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108461"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2024.115824"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2019.05.350"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.03.019"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215996"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202404350"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5SC04236D"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202005686"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00070A"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b06710"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c04196"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141779"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124592"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3043905"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202308651"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2024.133281"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.09.036"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15131b"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00134"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules30061270"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c00818"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6b02272"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2024.115603"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03562"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00038"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2023.128887"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202514192","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202514192","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202514192","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T09:29:30Z","timestamp":1783934970000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202514192"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3,19]]},"references-count":39,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2026,5]]}},"alternative-id":["10.1002\/smll.202514192"],"URL":"https:\/\/doi.org\/10.1002\/smll.202514192","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,3,19]]},"assertion":[{"value":"2025-11-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-10","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e14192"}}