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The versatile coordination between organic ligands and metal centers enables precise incorporation of metallic species within carbon matrix, offering exceptional atomic dispersion control. Herein, as evidenced by HAADF\u2010STEM and XAS, a bimetallic\u2010bridged coordination architecture featuring a ZnMn\u2010N\n                    <jats:sub>8<\/jats:sub>\n                    atomic structure is rationally fabricated. In a custom\u2010built gas\u2010solid phase electrocatalytic system for formaldehyde (HCHO) degradation, it exhibits 63.8% HCHO decomposition efficiency with 92.3% CO\n                    <jats:sub>2<\/jats:sub>\n                    selectivity. Density functional theory (DFT) calculations reveal that the bridged metal\u2010nitrogen coordination modulates the\n                    <jats:italic>d<\/jats:italic>\n                    \u2010band center, facilitating Zn\u2010to\u2010Mn electron transfer. This electronic redistribution creates electron\u2010deficient Zn active sites that enhance oxygen\u2010binding with HCHO through optimized orbital hybridization, thereby boosting electrocatalytic conversion efficiency. This work not only extends bimetallic\u2010bridged coordination catalysts from liquid\u2010phase to gas\u2010phase applications, but also provides fundamental insights into gaseous HCHO removal.\n                  <\/jats:p>","DOI":"10.1002\/smll.202514538","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T10:09:13Z","timestamp":1773050953000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Synergistic Catalysis at Zn\u2013Mn Dual\u2010Atoms Sites for Efficient Electrocatalytic Oxidation of Formaldehyde"],"prefix":"10.1002","volume":"22","author":[{"given":"Yang","family":"Li","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanling","family":"Qiu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiming","family":"Qian","sequence":"additional","affiliation":[{"name":"State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco\u2010Environmental Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco\u2010Environmental Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolong","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaole","family":"Gong","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengyu","family":"Cao","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujia","family":"He","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiuzhang","family":"Zheng","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Institute for Graphene Applied Technology Innovation, State Key Laboratory of Bio\u2010Fibers and Eco\u2010Textiles Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueying","family":"Cao","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Linyi University  Linyi P. 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