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This study proposes an innovative strategy for constructing a porous CuO@ fluorinated graphdiyne (F\u2010GDY) composite anode guided by a F\u2010GDY coating. The synergistic effect of Cu(OH)\n                    <jats:sub>2<\/jats:sub>\n                    core contraction and F\u2010GDY shell confinement led to the formation of a porous CuO structure while preserving the well\u2010defined linear array morphology. The interfacial charge transfer between F\u2010GDY and CuO modulates the electronic structure of CuO, significantly enhancing electron transport efficiency and sodium ion adsorption capacity. The porous structure effectively accommodates volume fluctuations during sodium\u2010ion insertion\/extraction, thereby facilitating the formation of a stable solid electrolyte interphase. Electrochemical tests demonstrate that the composite anode exhibits high reversible capacity (681 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 100 cycles at 50\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and excellent long\u2010term cycling stability (maintaining 278 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 1250 cycles at 2000\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Mechanistic analysis further confirms that the sodium storage process is predominantly capacitive and possesses a high ionic diffusion coefficient. This study provides a new perspective for developing high\u2010stability anode materials for SIBs that can accommodate volume changes.\n                  <\/jats:p>","DOI":"10.1002\/smll.202514822","type":"journal-article","created":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T12:44:04Z","timestamp":1768826644000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["The Preparation of Porous CuO@F\u2010GDY Nano\u2010Arrays for High\u2010Performance Sodium\u2010Ion Battery Anodes"],"prefix":"10.1002","volume":"22","author":[{"given":"Zhihui","family":"Zhang","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences  Beijing P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. 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