{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T20:25:07Z","timestamp":1792614307691,"version":"4.5.0"},"reference-count":47,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100022963","name":"Key Research and Development Program of Zhejiang Province","doi-asserted-by":"publisher","award":["2022C01049"],"award-info":[{"award-number":["2022C01049"]}],"id":[{"id":"10.13039\/100022963","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52273095"],"award-info":[{"award-number":["52273095"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475130"],"award-info":[{"award-number":["22475130"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Stimuli\u2010responsive nanopesticide delivery systems have attracted increasing attention due to their potential for controlled release and targeted application. However, their practical use in agriculture is often hindered by poor foliar retention, limited UV stability, and uncontrolled release behaviour. In this study, a grape\u2010pedicel\u2010like nanocarrier was constructed via in situ integration of cellulose nanocrystals (CNCs) with zeolitic imidazolate frameworks (ZnMOFs), which effectively encapsulated acetamiprid (Ace) and exhibited enhanced leaf adhesion and sustained\u2010release performance. The release of ACE was triggered by naturally occurring organic acids (e.g., oxalic acid) generated during plant metabolism, enabling a pH\u2010responsive behaviour under mildly acidic conditions (pH = 5). The cumulative release reached 85.9%, and the release kinetics followed the Ritger\u2013Peppas model. Compared with commercial formulations, Ace@CNC\/ZnMOFs showed superior dispersibility and significantly improved foliar adhesion (28.9\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), as well as enhanced UV resistance (65.1%) and rainfastness (61.3%). Moreover, the nanocarriers exhibited improved insecticidal activity (LC\n                    <jats:sub>50<\/jats:sub>\n                    = 11.9\u00a0mg\/L)\u00a0and reduced toxicity toward non\u2010target organisms, such as zebrafish. Life cycle assessment (LCA) further confirmed its advantages in resource efficiency and environmental sustainability. Overall, this work presents a multifunctional nanopesticide system with stimuli responsiveness to integrate strong adhesion and compatibility, offering a promising strategy for sustainable agricultural applications.\n                  <\/jats:p>","DOI":"10.1002\/smll.202514881","type":"journal-article","created":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T14:21:04Z","timestamp":1778854864000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Cellulose Nanocrystal\/Zn\u2010MOF Nanocarriers for Enhanced Foliar Adhesion, pH\u2010Responsive Release, and Efficient Pesticide Delivery"],"prefix":"10.1002","volume":"22","author":[{"given":"Zilu","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Continuing Education Zhejiang Sci\u2010Tech University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Somia Yassin Hussain","family":"Abdalkarim","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6543-5924","authenticated-orcid":false,"given":"Hou\u2010Yong","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Bio\u2010based Fiber Materials Zhejiang Sci\u2010Tech University  Hangzhou China"},{"name":"Department of Chemical Engineering Waterloo Institute for Nanotechnology University of Waterloo  Waterloo Ontario Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,15]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201041878\u20103"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43016\u2010025\u201001158\u20103"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43017\u2010025\u201000673\u2010y"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ade2232"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ps.6964"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139052"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202506319"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2024.171472"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202504824"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.161710"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1186\/s12974\u2010024\u201003215\u20103"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.140167"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.2c07466"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2023.10.060"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c12352"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151301"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151193"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2023.139922"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061604\u20105"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202424591"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2023.128834"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.134297"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/d3gc00328k"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.4c00698"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045546\u2010y"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c02856"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2022.160610"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2021.09.033"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodhyd.2024.110141"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153330"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbpol.2024.123185"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2021.111254"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.3389\/fbioe.2023.1197484"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.163416"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2025.138364"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6377"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.2c00353"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130143"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147357"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.3390\/agronomy12092148"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev\u2010ento\u2010121423\u2010012130"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202305693"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbpc.2008.11.006"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c03451"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma12244119"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1080\/23308249.2014.987209"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adq2110"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202514881","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202514881","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202514881","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date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