{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T09:05:48Z","timestamp":1791623148554,"version":"4.3.4"},"reference-count":83,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T00:00:00Z","timestamp":1769817600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T00:00:00Z","timestamp":1769817600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of multipurpose adsorbents for highly efficient separation of various gas mixtures is of great importance; this task becomes highly challenging when the guest constituents have almost similar physicochemical properties. Although many adsorbents have been developed so far targeting flue and biogas separations, natural gas purification, and C\n                    <jats:sub>2<\/jats:sub>\n                    \u2010hydrocarbon separations; multipurpose materials with high effectivities for all such gas mixtures separations by a single platform are elusive. Herein, we developed a new 3D interpenetrated hydro\u2010stable\n                    <jats:bold>MOF: IITKGP\u201021<\/jats:bold>\n                    , which displayed impressive capability for C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    , C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    , C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    , and C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    separations even at ambient conditions while maintaining an excellent trade\u2010off between high sorption capacity and separation selectivity. Most importantly, breakthrough simulations not only unveiled the efficient separation capabilities in binary mixtures but also highlighted the effectivity of one\u2010step methane purification with high purity from quaternary (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    ) mixtures mimicking natural gas composition. Moreover, the facile bulk scalability, ease in accessibility, excellent recyclability, and framework stability further validated the multi\u2010purpose gas separation capability of the developed framework.\n                  <\/jats:p>","DOI":"10.1002\/smll.72629","type":"journal-article","created":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T11:37:37Z","timestamp":1769859457000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["A Chemically Robust 3D Interpenetrated MOF Toward One\u2010Step Methane Purification Along with Six Other Multipurpose Gas Separations"],"prefix":"10.1002","volume":"22","author":[{"given":"Rupam","family":"Sahoo","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bikram","family":"Pramanik","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajamani","family":"Krishna","sequence":"additional","affiliation":[{"name":"Van\u2018t Hoff Institute for Molecular Sciences University of Amsterdam  Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Madhab C.","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,31]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202207197"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00551"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213998"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC04645K"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500970"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c02614"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210012"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2022.122312"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001611"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139642"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214628"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c03371"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202500851"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2020.117749"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE01886F"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA07584F"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.162121"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2022.07.005"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.012"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.138034"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c08726"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.124208"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA06511E"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216291"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.170918"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.129620"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03275"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201806445"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00756C"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.4c00336"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2019.100006"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215660"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/cbe.3c00114"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.130492"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QM00430A"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215924"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010023\u201001277\u2010z"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c13524"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18209"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202404834"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141795"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202411456"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar6833"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202407701"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202208182"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213173"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202500324"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QM00007A"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1025c18608"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047268\u20107"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adz3219"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.7b00197"},{"key":"e_1_2_6_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002603"},{"key":"e_1_2_6_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.128267"},{"key":"e_1_2_6_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202309281"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201900058"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202302677"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202304581"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.05.001"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5IM00067J"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202409939"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300821"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202402486"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202404756"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c02275"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201044424\u20103"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c18370"},{"key":"e_1_2_6_69_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005310\u2010y"},{"key":"e_1_2_6_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202515511"},{"key":"e_1_2_6_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00325"},{"key":"e_1_2_6_72_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adz5237"},{"key":"e_1_2_6_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202501491"},{"key":"e_1_2_6_74_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2025.03.120"},{"key":"e_1_2_6_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c01767"},{"key":"e_1_2_6_76_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215301"},{"key":"e_1_2_6_77_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202405561"},{"key":"e_1_2_6_78_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2024.115641"},{"key":"e_1_2_6_79_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA07830J"},{"key":"e_1_2_6_80_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA07363A"},{"key":"e_1_2_6_81_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2017.11.056"},{"key":"e_1_2_6_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c02218"},{"key":"e_1_2_6_83_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.2c00003"},{"key":"e_1_2_6_84_1","doi-asserted-by":"publisher","DOI":"10.1021\/cbe.3c00057"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.72629","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.72629","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.72629","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,28]],"date-time":"2026-03-28T16:48:44Z","timestamp":1774716524000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.72629"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,31]]},"references-count":83,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2026,3]]}},"alternative-id":["10.1002\/smll.72629"],"URL":"https:\/\/doi.org\/10.1002\/smll.72629","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,31]]},"assertion":[{"value":"2025-12-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-19","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-31","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e72629"}}