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Herein, we report a solvent\u2010induced reverse\u2010Ostwald ripening process between two atomically precise silver clusters, Ag\n                    <jats:sub>56<\/jats:sub>\n                    and Ag\n                    <jats:sub>45<\/jats:sub>\n                    , which exhibit solvent\u2010dependent structure variation: Ag\n                    <jats:sub>56<\/jats:sub>\n                    remains stable in dichloromethane, whereas exposure to pentane induces conversion to Ag\n                    <jats:sub>45<\/jats:sub>\n                    . The compositions and structures of both clusters were determined by electrospray ionization mass spectrometry (ESI\u2010MS) and single\u2010crystal X\u2010ray diffraction (SXRD). Structure analysis indicates that the Ag\n                    <jats:sub>45<\/jats:sub>\n                    forms via fragmentation and reorganization of the Ag\n                    <jats:sub>56<\/jats:sub>\n                    framework, distinct from the conventional Ostwald ripening observed in larger nano\u2010systems. Although Ag\n                    <jats:sub>45<\/jats:sub>\n                    and Ag\n                    <jats:sub>56<\/jats:sub>\n                    share certain structural similarities, Ag\n                    <jats:sub>45<\/jats:sub>\n                    exhibits superior stability and higher catalytic activity for the reduction of 4\u2010nitrophenol (4\u2010NP) than Ag\n                    <jats:sub>56<\/jats:sub>\n                    . Density functional theory (DFT) calculations further elucidate the catalytic reduction pathway on Ag\n                    <jats:sub>45<\/jats:sub>\n                    . This work demonstrates a solvent\u2010mediated reverse\u2010Ostwald ripening pathway in silver clusters, providing atomic\u2010level insights into active site construction and offering a blueprint for designing robust, cluster\u2010based catalysts.\n                  <\/jats:p>","DOI":"10.1002\/smll.73239","type":"journal-article","created":{"date-parts":[[2026,3,27]],"date-time":"2026-03-27T10:13:53Z","timestamp":1774606433000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Solvent\u2010Induced Reverse\u2010Ostwald Ripening: Structure Conversion from Ag\n                    <sub>56<\/sub>\n                    to Ag\n                    <sub>45<\/sub>\n                    Clusters and Its Impact on Catalytic Reduction of 4\u2010Nitrophenol"],"prefix":"10.1002","volume":"22","author":[{"given":"Huixin","family":"Xiang","sequence":"first","affiliation":[{"name":"Frontiers Science Center for Flexible Electronics, State Key Laboratory of Flexible Electronics (LoFE), Institute of Flexible Electronics (IFE) Northwestern Polytechnical University  Xi'an China"},{"name":"Fujian Key Laboratory of Flexible Electronics, Strait Institute of Flexible Electronics Fujian Normal University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaxi","family":"Lei","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology Ningbo University  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Sun","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Flexible Electronics, Strait Institute of Flexible Electronics Fujian Normal University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fenzhen","family":"Chen","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Flexible Electronics, Strait Institute of Flexible Electronics Fujian Normal University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenhao","family":"Ruan","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Flexible Electronics, Strait Institute of Flexible Electronics Fujian Normal University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0651-9562","authenticated-orcid":false,"given":"Wen Wu","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology Ningbo University  Ningbo 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