{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T11:57:44Z","timestamp":1781524664519,"version":"3.54.1"},"reference-count":38,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T00:00:00Z","timestamp":1775520000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T00:00:00Z","timestamp":1775520000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004912","name":"Sichuan University","doi-asserted-by":"publisher","award":["2023SCUH0076"],"award-info":[{"award-number":["2023SCUH0076"]}],"id":[{"id":"10.13039\/501100004912","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Photoelectrochemical (PEC) upcycling of plastic waste into value\u2010added chemicals and hydrogen fuel offers a sustainable approach to mitigate pollution while producing clean energy. Here, we report a flow\u2010through ternary heterojunction membrane photoanode (CoOCl\/SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    \/TiO\n                    <jats:sub>2<\/jats:sub>\n                    ) that integrates membrane\u2010confined mass transport with self\u2010adaptive cocatalyst reconstruction to enable selective PET photoreforming. The optimized CoOCl\/SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    \/TiO\n                    <jats:sub>2<\/jats:sub>\n                    membrane achieves a GA production rate of 10.76\u00a0\u00b5mol cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with 80% selectivity, alongside a hydrogen evolution rate of 4.49\u00a0\u00b5mol cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , significantly outperforming TiO\n                    <jats:sub>2<\/jats:sub>\n                    and SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    \/TiO\n                    <jats:sub>2<\/jats:sub>\n                    binary photoanodes. Post\u2010reaction analysis reveals that CoOCl undergoes ion displacement reactions in the alkaline electrolyte and reconstructs into \u03b2\u2010CoOOH, which serves as an efficient hole transfer cocatalyst and drives selective oxidation of ethylene glycol from PET via a\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    pathway. This dynamic reconstruction ensures high durability over repeated cycles (7% decay after five cycles). Such monolithic flow\u2010through membrane architecture and reconstruction of CoOCl into \u03b2\u2010CoOOH synergistically enhance mass transport, charge utilization, and oxidation selectivity. This work thus establishes a membrane photoelectrode technology for sustainable plastic valorization and solar fuel production.\n                  <\/jats:p>","DOI":"10.1002\/smll.73306","type":"journal-article","created":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T18:15:46Z","timestamp":1775585746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Photoelectrochemical Reforming of PET Plastics using a Ternary CoOCl\/SrTiO\n                    <sub>3<\/sub>\n                    \/TiO\n                    <sub>2<\/sub>\n                    Heterojunction Membrane Electrode"],"prefix":"10.1002","volume":"22","author":[{"given":"Shuai","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nashwan. H. 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