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Poly(vinylidene fluoride\u2010\n                    <jats:italic>co<\/jats:italic>\n                    \u2010hexafluoropropylene)\u2010\n                    <jats:italic>g<\/jats:italic>\n                    \u2010poly\u20102\u2010(dimethylamino)ethyl methacrylate\u2010based zwitterionic composite membranes were synthesized via ATRP\u2010mediated grafting, followed by N\u2010alkylation with 1,3\u2010propanesultone. The membrane architecture was further tailored by incorporating UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    and sulfonated graphitic carbon nitride (sgC\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    ) as complexed fillers, forming a hierarchically organized ionic framework that reconciles the trade\u2010off between ionic conductivity and fuel\/electrolyte permeability. The optimized PDS\u201011 membrane (UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    : sgC\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    = 1:1, 1% w\/w) exhibited high ion exchange capacity and proton conductivity (K\n                    <jats:sup>m<\/jats:sup>\n                    = 27.1 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 80\u00b0C), 2.65 times higher than pristine PDS. Its low VO\n                    <jats:sup>2+<\/jats:sup>\n                    permeability and high ion selectivity arise from synergistic acid\u2010base and H\u2010bonding interactions between \u2010NH\/\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    and \u2010SO\n                    <jats:sub>3<\/jats:sub>\n                    H groups, complemented by non\u2010covalent interactions and physical blocking within the membrane matrix. The porous UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    and layered sgC\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    improved water retention and structural robustness, yielding 89% power retention at 70% RH in PEMFCs, with a mere OCV decay rate of 1.6 mV h\n                    <jats:sup>\u22121<\/jats:sup>\n                    over 50 h. PDS\u201011 also exhibited exceptional VRFB performance with CE, VE, and EE of 97.41%, 76.32%, and 74.34%, respectively,, over 200 cycles at 120 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    (42.3% of capacity retention after 100 cycles with 620 min of OCV retention).\n                  <\/jats:p>","DOI":"10.1002\/smll.73441","type":"journal-article","created":{"date-parts":[[2026,4,21]],"date-time":"2026-04-21T12:44:07Z","timestamp":1776775447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Sulfonated Graphitic Carbon Nitride\/UiO\u201066\u2010NH\n                    <sub>2<\/sub>\n                    Infused PVDF\u2010\n                    <i>co<\/i>\n                    \u2010HFP\u2010Tailored Zwitterionic Membranes for Low\u2010Humidity Hydrogen Fuel Cells and Vanadium Flow 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