{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:54:26Z","timestamp":1786978466028,"version":"build-2736575974"},"reference-count":39,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2026,4,23]],"date-time":"2026-04-23T00:00:00Z","timestamp":1776902400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,23]],"date-time":"2026-04-23T00:00:00Z","timestamp":1776902400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22075082"],"award-info":[{"award-number":["22075082"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Garnet\u2010type solid\u2010state electrolyte Li\n                    <jats:sub>6.4<\/jats:sub>\n                    La\n                    <jats:sub>3<\/jats:sub>\n                    Zr\n                    <jats:sub>1.4<\/jats:sub>\n                    Ta\n                    <jats:sub>0.6<\/jats:sub>\n                    O\n                    <jats:sub>12<\/jats:sub>\n                    (LLZTO) is regarded as one of the most promising electrolytes due to its exceptional overall performance. However, the development of garnet\u2010based all\u2010solid\u2010state lithium metal batteries (ASSLMBs) is significantly impeded by the poor air stability of LLZTO and the uneven contact of Li\/LLZTO. In this work, a uniformly porous electrolyte (PLLZTO) is fabricated via sodium dodecyl benzene sulfonate (SDBS) assisted HNO\n                    <jats:sub>3<\/jats:sub>\n                    etching. Owing to the hydrophobicity of the C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>25<\/jats:sub>\n                    \u2010 chain of SDBS, the storage time of PLLZTO in air is increased to more than 7 days. By adsorbing and filling graphene oxide quantum dots and LiNO\n                    <jats:sub>3<\/jats:sub>\n                    in the surface of PLLZTO, a 3D ionic conductor interface containing Li\n                    <jats:sub>3<\/jats:sub>\n                    N\/LiN\n                    <jats:sub>x<\/jats:sub>\n                    O\n                    <jats:sub>y<\/jats:sub>\n                    \/Li\n                    <jats:sub>2<\/jats:sub>\n                    O (LNO@PLLZTO) is constructed by in situ reaction with lithium. Benefiting from the LNO@PLLZTO interface, Li|LNO@PLLZTO|Li achieves a low interfacial impedance of 4 \u03a9 cm\n                    <jats:sup>2<\/jats:sup>\n                    and a high critical current density of 1.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , demonstrating stable cycling for 3000\u00a0h at 0.2\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The assembled ASSLMBs with polyethylene oxide (PEO)\u2010based functional layer retains 92% capacity retention after 250 cycles at 1 C. This work not only significantly enhances the air stability of LLZTO but also achieves an ultra\u2010lithiophilic interface, thus laying a foundation for the realization of high\u2010performance ASSLMBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.73502","type":"journal-article","created":{"date-parts":[[2026,4,23]],"date-time":"2026-04-23T10:03:30Z","timestamp":1776938610000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Three\u2010Dimensional High\u2010Efficiency Superlithiophilic Interface Toward Air\u2010Stable Garnet\u2010Based All\u2010Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Guoxiang","family":"Zheng","sequence":"first","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education Shanghai Engineering Research Center of Hierarchical Nanomaterials School of Materials Science and Engineering East China University of 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