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Herein, it is reported that a Mo\u2010doped TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/Sb\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    nanotube (Mo\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/Sb\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    ) S\u2010scheme heterojunction in which dopant\u2010induced electronic modulation and interfacial built\u2010in electric field (BIEF) engineering operate cooperatively to enable directional charge transport and accelerated oxidation kinetics. Mo incorporation increases the TiO\n                    <jats:sub>2<\/jats:sub>\n                    work function and amplifies the Fermi\u2010level offset relative to Sb\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    , generating a strengthened BIEF that promotes S\u2010scheme charge transfer while preserving strong redox potentials. Spectroscopic and photoelectrochemical analyses reveal prolonged carrier lifetime, enhanced interfacial charge mobility, and the formation of Ti\u2010S and Mo\u2010S covalent pathways that facilitate rapid electron flow and reactive oxygen species (ROS) generation. Density functional theory (DFT) calculations further demonstrates that Mo doping downshifts the d\u2010band center, strengthens reactant adsorption, and significantly lowers the energy barrier for benzoic acid ring\u2010opening, the rate\u2010determining step in toluene mineralization. As a result, the optimized catalyst achieves nearly complete toluene degradation with high CO\n                    <jats:sub>2<\/jats:sub>\n                    selectivity under visible light. This work establishes a synergistic strategy combining dopant\u2010induced electronic tuning and S\u2010scheme heterointerface design to overcome kinetic bottlenecks in aromatic VOC mineralization, offering a pathway for advanced air purification.\n                  <\/jats:p>","DOI":"10.1002\/smll.73750","type":"journal-article","created":{"date-parts":[[2026,5,26]],"date-time":"2026-05-26T10:04:21Z","timestamp":1779789861000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dopant\u2010Strengthened S\u2010Scheme Heterointerfaces in Mo\u2010TiO\n                    <sub>2<\/sub>\n                    \/Sb\n                    <sub>2<\/sub>\n                    S\n                    <sub>3<\/sub>\n                    Nanotubes Enable Built\u2010In Field\u2010Driven Charge Channels for Efficient Visible\u2010Light Mineralization of Aromatic VOCs"],"prefix":"10.1002","volume":"22","author":[{"given":"Huaikai","family":"Yang","sequence":"first","affiliation":[{"name":"Hubei Key Laboratory of Multi\u2010media Pollution Cooperative Control in Yangtze Basin, School of Environmental Science &amp; Engineering Huazhong University of Science and Technology (HUST)  Wuhan Hubei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongmei","family":"Li","sequence":"additional","affiliation":[{"name":"Hunan Joint International Research Center For Carbon Dioxide Resource Utilization, State Key Laboratory of Powder Metallurgy, School of Physics Central South University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shirui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hubei Key Laboratory of Multi\u2010media Pollution Cooperative Control in Yangtze Basin, School of Environmental Science &amp; Engineering Huazhong University of Science and Technology (HUST)  Wuhan 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