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To address these issues, we demonstrate the construction of yolk\u2010double\u2010shell ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    \/N\u2010doped carbon@carbon (ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    \/NC@C) polyhedra through a Kirkendall\u2010effect\u2010mediated tannic acid (TA) etching strategy using a resorcinol\u2010formaldehyde (RF) coated ZIF\u20108 precursor. This rationally designed architecture confers several synergistic advantages: (i) the N\u2010doped carbon matrix derived from ZIF\u20108\/TA\u2010Zn and the carbon shell from RF form a continuous conductive network, facilitating rapid charge transfer; (ii) the yolk\u2010double\u2010shell framework with ample internal void space effectively accommodates the volume variations, preserving structural integrity; and (iii) the outer carbon shell serves as a physical barrier against polysulfide dissolution, enhancing reaction reversibility. Benefiting from this multi\u2010synergistic engineering, the novel ZnPS\n                    <jats:sub>3<\/jats:sub>\n                    \/NC@C anode exhibits impressive sodium storage performance, delivering a high charge\/discharge capacity of 925.7\/1128.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , along with a remarkable long\u2010term cyclability with 96.9% capacity retention over 2000 cycles at 2.0 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work establishes a generalizable design paradigm integrating morphological manipulation with multi\u2010component compositing for developing advanced electrode materials.\n                  <\/jats:p>","DOI":"10.1002\/smll.73833","type":"journal-article","created":{"date-parts":[[2026,5,17]],"date-time":"2026-05-17T16:27:53Z","timestamp":1779035273000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Yolk\u2010Double\u2010Shell ZnPS\n                    <sub>3<\/sub>\n                    \/NC@C Polyhedra Engineered via Kirkendall\u2010Effect\u2010Driven Etching for Superior Sodium Storage"],"prefix":"10.1002","volume":"22","author":[{"given":"Ming","family":"Yue","sequence":"first","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang 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Physics and Materials Science Nanchang University  Nanchang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen","family":"Chen","sequence":"additional","affiliation":[{"name":"China State Key Laboratory of Marine Resource Utilization in South China Sea Hainan University  Haikou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4586-4059","authenticated-orcid":false,"given":"Shuijin","family":"Lei","sequence":"additional","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang 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