{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T17:31:11Z","timestamp":1786987871452,"version":"build-2736575974"},"reference-count":58,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2026,5,21]],"date-time":"2026-05-21T00:00:00Z","timestamp":1779321600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,21]],"date-time":"2026-05-21T00:00:00Z","timestamp":1779321600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB2502000"],"award-info":[{"award-number":["2022YFB2502000"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Efficient ion transport plays an important role in lots of applications, especially in advancing electrochemical energy storage technologies. In this work, quasi\u2010solid\u2010state electrolytes (QSSEs) with continuous and low\u2010barrier Li\n                    <jats:sup>+<\/jats:sup>\n                    pathways are created by concurrent tuning of the compact geometric space of sub\u2010nanometer pores and their chemical functionality. The compact geometric space limits the entry of excess solvent and shortens Li\n                    <jats:sup>+<\/jats:sup>\n                    migration distances, while electronegative coordination sites strengthen electrostatic interactions and optimize the primary solvation structure, thereby suppressing anion migration. The resulting modified electrolytes exhibit a high ionic conductivity of 2.33 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number of 0.90 at room temperature, concurrently achieving high conductivity and Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010dominant conduction. When applied in lithium\u2010metal batteries (LMBs), the electrolyte enables superior rate capability and long\u2010term cycling stability. This study highlights the potential of sub\u2010nanometer pore functionalization as a general materials design strategy for developing high\u2010performance electrolytes, providing a promising direction for next\u2010generation energy storage systems. Meanwhile, the distinctive ion transport behavior observed in sub\u2010nanometer confined environments offers new opportunities for a wide range of applications related to ion transport.\n                  <\/jats:p>","DOI":"10.1002\/smll.73837","type":"journal-article","created":{"date-parts":[[2026,5,21]],"date-time":"2026-05-21T09:30:52Z","timestamp":1779355852000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tuning the Ion Transfer Behavior to Approaching Near\u2010Unity Li\n                    <sup>+<\/sup>\n                    Transference via Pore Engineering"],"prefix":"10.1002","volume":"22","author":[{"given":"Xingkai","family":"Jia","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Zhejiang University  Hangzhou China"},{"name":"ZJU\u2011Hangzhou Global Scientific and Technological Innovation Center Zhejiang University  Hangzhou 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