{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T05:01:08Z","timestamp":1790744468382,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","issue":"34","license":[{"start":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T00:00:00Z","timestamp":1779926400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T00:00:00Z","timestamp":1779926400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100018617","name":"Liaoning Revitalization Talents Program","doi-asserted-by":"publisher","award":["XLYC2403047"],"award-info":[{"award-number":["XLYC2403047"]}],"id":[{"id":"10.13039\/501100018617","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22574017"],"award-info":[{"award-number":["22574017"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017683","name":"Dalian Science and Technology Innovation Fund","doi-asserted-by":"publisher","award":["2024JJ13GX044"],"award-info":[{"award-number":["2024JJ13GX044"]}],"id":[{"id":"10.13039\/501100017683","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Organic materials with high capacity and sustainability are widely used in aqueous zinc\u2010ion batteries (ZIBs), yet organic materials with multi\u2010redox centers and stable structures are seldom reported. Herein, we design a novel \u03c0\u2010conjugated organic molecule with twelve C\u2550O and C\u2550N active sites, BDQDT (Bisdipyrido[4,3\u2010a:3\u2019,4\u2019\u2010c]quinoxaline[3,2\u2010a:2\u2019,3\u2019\u2010h]\u201011,24\u2010dihydrophenazine\u201010,12,23,25\u2010tetraone), enabling strong electron delocalization, reinforced \u03c0\u2013\u03c0 stacking, and suppressed dissolution. As a result, BDQDT ZIBs exhibit excellent rate capability with 84.0 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 20 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and outstanding cycling stability after 12\u00a0000 cycles. Besides, In situ characterizations combined with DFT calculations confirm Zn\n                    <jats:sup>2+<\/jats:sup>\n                    \/H\n                    <jats:sup>+<\/jats:sup>\n                    co\u2010insertion mechanism. The optimized discharged structure is identified as BDQDT\u20101Zn\u201010H, binding from one BDQDT molecule with one zinc ion and ten protons. Impressively, flexible Zn\u2010ion device of BDQDT maintains stable properties under various mechanical deformations, and could power a humidity sensor. Prospectively, this work would build molecular engineering strategies for high\u2010capacity and stable organic ZIBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.73961","type":"journal-article","created":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T08:40:32Z","timestamp":1779957632000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Molecular Engineering of \u03c0\u2010Conjugated C\u2550O\/C\u2550N Cathode for Ultrastable Organic Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Zhangyu","family":"Wang","sequence":"first","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaodong","family":"Geng","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Yang","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quanli","family":"Liu","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqian","family":"Li","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinghua","family":"Deng","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhouxiaolong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Liu","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wencheng","family":"Li","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6023-2618","authenticated-orcid":false,"given":"Mianqi","family":"Xue","sequence":"additional","affiliation":[{"name":"Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuqian","family":"Jiang","sequence":"additional","affiliation":[{"name":"Key laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongting","family":"Ma","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6029-6200","authenticated-orcid":false,"given":"Nan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,28]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0063-z"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01304-1"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217671"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-021-00834-z"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403712"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48368-0"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303967"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06668"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA01400B"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00349E"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cbe.3c00120"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00018D"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103799"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA06641J"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.217046"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202404815"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202103617"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408292"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03223"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-24701-9"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC07013A"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202204005"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aao1761"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201807121"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202219136"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141336"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.125898"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202506749"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916529"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40969-5"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.022.202202276"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0216272"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202409946"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202010049"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137289"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09290"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201900750"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.06.049"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116289"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c10539"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.228401"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.02.022"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE02961H"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c00903"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym11111774"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-024-00404-w"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.73961","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.73961","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.73961","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,17]],"date-time":"2026-06-17T19:00:24Z","timestamp":1781722824000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.73961"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,28]]},"references-count":47,"journal-issue":{"issue":"34","published-print":{"date-parts":[[2026,6]]}},"alternative-id":["10.1002\/smll.73961"],"URL":"https:\/\/doi.org\/10.1002\/smll.73961","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,28]]},"assertion":[{"value":"2026-01-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-13","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e73961"}}