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This study introduces an interfacial phase reconstruction strategy by leveraging the confined induction capability of MOF\u20105. Mn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    ions preloaded in the electrolyte (2\u00a0M ZnSO\n                    <jats:sub>4<\/jats:sub>\n                    and 0.2\u00a0M MnSO\n                    <jats:sub>4<\/jats:sub>\n                    ) preferentially engage with Zn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    at the MOF\u20105 surface, forming a dynamic and reversible in situ ZnMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    interphase that enhances the performance and stability of AZIBs. ZnMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    functions as a self\u2010expanding, reversible interfacial host that is vital for managing energy storage and ensuring structural stability. The presence of MOF\u20105 provides confined nucleation sites that enable the selective deposition of ZnMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    , thereby protecting the underlying MnO\n                    <jats:sub>2<\/jats:sub>\n                    from collapse and dissolution. With this dynamic interfacial engineering, the CC\/MO@MOF\u20105 electrode demonstrates a reversible capacity of 173.7\u00a0mAh\u00a0g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    at 0.1\u00a0A\u00a0g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    and gradually activates to 79\u00a0mAh\u00a0g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    after 5000 cycles at 1\u00a0A\u00a0g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    . The electrochemical reversibility of ZnMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    and its voltage\u2010dependent phase evolution are systematically investigated. This work redefines ZnMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    as a tunable and electrochemically active main storage phase and establishes an electrolyte\u2013interphase co\u2010design strategy for aqueous multivalent ion batteries under extreme conditions.\n                  <\/jats:p>","DOI":"10.1002\/smll.73963","type":"journal-article","created":{"date-parts":[[2026,5,26]],"date-time":"2026-05-26T10:30:31Z","timestamp":1779791431000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electrolyte\u2010Induced Interfacial ZnMn\n                    <sub>2<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    Formation on MnO\n                    <sub>2<\/sub>\n                    @MOF\u20105 Cathodes for Ultra\u2010Stable Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0448-3380","authenticated-orcid":false,"given":"Zhi\u2010Ting","family":"Huang","sequence":"first","affiliation":[{"name":"Department of Chemical and Materials Engineering Tunghai University  Taichung Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi\u2010Xuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Materials Engineering Tunghai University  Taichung Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jyun\u2010Wei","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemical and Materials Engineering Tunghai University  Taichung Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting\u2010Yu","family":"Lo","sequence":"additional","affiliation":[{"name":"Department of Chemical and Materials Engineering Tunghai University  Taichung Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Su\u2010Yang","family":"Hsu","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Research Center (NSRRC)  Hsinchu Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3129-2750","authenticated-orcid":false,"given":"Soorathep","family":"Kheawhom","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Faculty of Engineering Chulalongkorn University  Bangkok Thailand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7859-246X","authenticated-orcid":false,"given":"Jeng\u2010Yu","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemical and Materials Engineering Tunghai University  Taichung Taiwan"},{"name":"Department of Chemical Engineering, Faculty of Engineering Chulalongkorn University  Bangkok 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