{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T21:10:02Z","timestamp":1791234602560,"version":"4.1.0"},"reference-count":32,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T00:00:00Z","timestamp":1780531200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T00:00:00Z","timestamp":1780531200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22501280"],"award-info":[{"award-number":["22501280"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22220102005"],"award-info":[{"award-number":["22220102005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2026J0011455"],"award-info":[{"award-number":["2026J0011455"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) to liquid ethanol has emerged as a critical research direction. Ethanol, which undergoes the same C\u2500C coupling process but requires more proton\u2010coupled electron transfer (PCET) steps than ethylene, which makes the enhancement of ethanol selectivity a significant challenge. Herein, polyaniline\u2010encapsulated Cu Nanowires (Cu@PANI\u20105) have been synthesized via a self\u2010assembly strategy. The Cu@PANI\u20105 with a 5\u00a0nm PANI shell achieves 80% multi\u2010carbon product selectivity and 42% ethanol Faradaic efficiency at 400\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    current density. In situ spectroscopy measurements and density functional theory calculations demonstrate that the PANI modification can regulate the *CO intermediate adsorption configuration from *CO\n                    <jats:sub>top<\/jats:sub>\n                    to *CO\n                    <jats:sub>bridge<\/jats:sub>\n                    on the Cu NWs interface, thereby effectively accelerates the PCET process of CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. When the ratio of *CO\n                    <jats:sub>top<\/jats:sub>\n                    to *CO\n                    <jats:sub>bridge<\/jats:sub>\n                    is regulated to 1:3 by modulating the thickness of the PANI shell, the C\u2500C coupling is most favorable. The balanced C\u2500C coupling and PCET hydrogenation processes under this ratio enhance the selectivity of ethanol. This work highlights that the *CO intermediate adsorption configuration is pivotal for CO\n                    <jats:sub>2<\/jats:sub>\n                    RR catalytic performance, providing valuable guidance for optimizing ethanol selectivity.\n                  <\/jats:p>","DOI":"10.1002\/smll.74080","type":"journal-article","created":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T11:16:54Z","timestamp":1780571814000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Polyaniline Encapsulated Cu Nanowires Steering *CO Adsorption Configuration to Enhance Ethanol Selectivity in CO\n                    <sub>2<\/sub>\n                    Electrocatalysis"],"prefix":"10.1002","volume":"22","author":[{"given":"Wan\u2010Feng","family":"Xiong","sequence":"first","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Han","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ji\u2010Long","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"},{"name":"College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ze","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Duan\u2010Hui","family":"Si","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou China"},{"name":"University of Chinese Academy of Science  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong\u2010Fang","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou China"},{"name":"University of Chinese Academy of Science  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2398-399X","authenticated-orcid":false,"given":"Rong","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou China"},{"name":"College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"},{"name":"University of Chinese Academy of Science  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,4]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100450\u2010y"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21234j"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2020.121782"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001633\u20104"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407748"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02124"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202301807"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC05441D"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214946"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.126064"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413005"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010019\u20101782\u20102"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02387"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417562"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02945"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA01115D"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413832"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201031427\u20109"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-021-00783-4"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08867"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202510680"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.165200"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121498"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u20100607\u20108"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011956"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202425636"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b02525"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501773"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b09598"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c08922"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518377"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74080","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.74080","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74080","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T11:16:54Z","timestamp":1785237414000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.74080"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,4]]},"references-count":32,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/smll.74080"],"URL":"https:\/\/doi.org\/10.1002\/smll.74080","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,4]]},"assertion":[{"value":"2026-03-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-27","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74080"}}