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In this work, we construct a nanosheet\u2010hollow core\u2010shell ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    @CeO\n                    <jats:sub>2<\/jats:sub>\n                    S\u2010scheme heterojunction via a facile hydrothermal approach, achieving the integration of efficient interfacial charge transfer with localized photothermal enhancement. Comprehensive characterizations and density functional theory calculations confirmed that the S\u2010scheme band alignment promotes directional charge migration and maintains strong redox potentials. Meanwhile, the engineered heterointerface and confined hollow cavity synergistically broaden light absorption, enrich CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption sites, and generate localized thermal fields that accelerate interfacial reaction kinetics. As a result, the ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    @CeO\n                    <jats:sub>2<\/jats:sub>\n                    heterojunction exhibits a CO yield of 96.21\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a selectivity of 87%, which is 2.87 and 7.81 times higher than that of pure ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    and CeO\n                    <jats:sub>2<\/jats:sub>\n                    , respectively. This work offers a new design paradigm for photothermal\u2010assisted S\u2010scheme photocatalysts in solar\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction.\n                  <\/jats:p>","DOI":"10.1002\/smll.74118","type":"journal-article","created":{"date-parts":[[2026,6,8]],"date-time":"2026-06-08T07:04:35Z","timestamp":1780902275000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Well\u2010Designed ZnIn\n                    <sub>2<\/sub>\n                    S\n                    <sub>4<\/sub>\n                    @CeO\n                    <sub>2<\/sub>\n                    Core\u2010Shell Photocatalysts With Photothermal Synergistic Enhancement for CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"22","author":[{"given":"Guohao","family":"Wang","sequence":"first","affiliation":[{"name":"College of Physics and Guizhou Province Key Laboratory For Photoelectric Technology and Application Guizhou University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuojun","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Physics and Guizhou Province Key Laboratory For Photoelectric Technology and Application Guizhou University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Shen","sequence":"additional","affiliation":[{"name":"College of Physics and Guizhou Province Key Laboratory For Photoelectric Technology and Application Guizhou University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilin","family":"Feng","sequence":"additional","affiliation":[{"name":"College of Physics and Guizhou Province Key Laboratory For Photoelectric Technology and Application Guizhou University  Guiyang 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