{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T17:25:30Z","timestamp":1786123530137,"version":"build-2736575974"},"reference-count":33,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T00:00:00Z","timestamp":1780963200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T00:00:00Z","timestamp":1780963200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22272008"],"award-info":[{"award-number":["22272008"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21872011"],"award-info":[{"award-number":["21872011"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22171062"],"award-info":[{"award-number":["22171062"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,8]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Semiconductor nanoclusters exhibit remarkable quantum confinement effects and ultranarrow size distributions, enabling highly selective absorption in the solar\u2010blind ultraviolet (also called UVC) region, making them promising candidates for UVC photoactive materials. However, poor charge transport and disordered aggregation have severely hindered their device applications. To overcome these limitations, we developed herein a soft\u2010template\u2010assisted, low\u2010temperature solvothermal method to synthesize triangular two\u2010dimensional (2D) ZnS cluster assemblies (CTAs) with lateral dimensions of \u223c100\u00a0nm, comprising uniform (ZnS)\n                    <jats:sub>34<\/jats:sub>\n                    clusters. These ZnS CTAs display a sharp, intense absorption peak at 258\u00a0nm with a steep cutoff at 268\u00a0nm, demonstrating exclusive UVC selectivity. To enhance charge transport, we integrated the ZnS CTAs with graphene oxide nanosheets (GOs) via solution mixing followed by thermal annealing to form ZnS CTAs\/GOs composites. Based on these composites, we fabricated self\u2010powered photoelectrochemical photodetectors (PEC PDs) with an averaged R\n                    <jats:sub>peak<\/jats:sub>\n                    \/R\n                    <jats:sub>280 nm<\/jats:sub>\n                    rejection ratio of 80, responsivity of 21.9\u00a0mA W\n                    <jats:sup>\u22121<\/jats:sup>\n                    , detectivity of 1.13 \u00d7 10\n                    <jats:sup>12<\/jats:sup>\n                    Jones, on\/off ratio of 5688, surpassing all previously reported ZnS\u2010 and ZnO\u2010based PDs. To our knowledge, this work represents the first demonstration of high\u2010quality cluster assemblies combining exclusive UVC absorption with superior charge transport for optoelectronic applications, thereby advancing the controlled synthesis and device integration of semiconductor nanoclusters.\n                  <\/jats:p>","DOI":"10.1002\/smll.74158","type":"journal-article","created":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T07:22:11Z","timestamp":1780989731000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Graphene Oxide Nanosheets\u2010Supported ZnS Cluster Triangle Assemblies Enabling Self\u2010Powered Solar\u2010Blind Photodetectors With Ultrahigh Selectivity and Sensitivity"],"prefix":"10.1002","volume":"22","author":[{"given":"Simeng","family":"Hao","sequence":"first","affiliation":[{"name":"Key Laboratory of Theoretical and Computational Photochemistry Ministry of Education College of Chemistry Beijing Normal University Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhao","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Theoretical and Computational Photochemistry Ministry of Education College of Chemistry Beijing Normal University Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Wei","sequence":"additional","affiliation":[{"name":"Key Laboratory of Theoretical and Computational Photochemistry Ministry of Education College of Chemistry Beijing Normal University Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qun","family":"Liu","sequence":"additional","affiliation":[{"name":"Technology Innovation Center of Nanosized Natural Products and New Materials of Hebei Province College of Chemical Engineering and Materials Handan University  Handan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Li","sequence":"additional","affiliation":[{"name":"Technology Innovation Center of Nanosized Natural Products and New Materials of Hebei Province College of Chemical Engineering and Materials Handan University  Handan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5554-7252","authenticated-orcid":false,"given":"Yunchao","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Theoretical and Computational Photochemistry Ministry of Education College of Chemistry Beijing Normal University Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,9]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02880262"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201806006"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2015.06.001"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202100695"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b11956"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201700264"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4829065"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.124337"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1109\/LPT.2004.829526"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3238571"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200901108"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010015\u20100723\u20100"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202302466"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1109\/LPT.2018.2849345"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TC03977A"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b20357"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10791"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502637q"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2013.04.003"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201200506"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3TC31899K"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC02467J"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c03015"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.4c00781"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75555"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2026.186094"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202514917"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202406308"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1109\/LPT.2020.2967795"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202501328"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.165031"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2022.09.300"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.3389\/fmats.2021.787613"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74158","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.74158","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74158","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:15:23Z","timestamp":1786115723000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.74158"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,9]]},"references-count":33,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2026,8]]}},"alternative-id":["10.1002\/smll.74158"],"URL":"https:\/\/doi.org\/10.1002\/smll.74158","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,9]]},"assertion":[{"value":"2026-02-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74158"}}