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Here, a new strategy to promote the solar\u2010light driven photocatalytic activity of ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    was proposed by introducing Rh single atom (SAs) into CeO\n                    <jats:sub>2<\/jats:sub>\n                    :Yb,Er\/ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    with photo\u2010thermo\u2010electric effects. The introduction of Rh SAs into ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    effectively suppresses charge recombination, and improves reaction rate through photo\u2010thermal effect. CeO\n                    <jats:sub>2<\/jats:sub>\n                    :Yb, Er converts NIR light into visible light via up\u2010conversion photo\u2010optical processes and generates high\u2010energy electrons via two\u2010photon photo\u2010electronic process, both of which can activate ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    . Large contact area and strong interface electric field between CeO\n                    <jats:sub>2<\/jats:sub>\n                    and ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    enhance photo\u2010electric conversion efficiency. The CeO\n                    <jats:sub>2<\/jats:sub>\n                    :Yb,Er\/Rh\u2010ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    exhibits a hydrogen production rate of up to 99.68 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10\u00b0C and 148.06 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with non\u2010temperature\u2010controlled conditions. Under mild conditions, the photocatalysts can convert glucose into high\u2010value\u2010added chemicals (e.g., arabinose) while simultaneously generating hydrogen. This work provides a new strategy to improve NIR light utilization efficiency and enhance charge\u2010carrier separation capability through photo\u2010thermo\u2010electric effects, promoting the production of green hydrogen and biomass conversion into high\u2010value\u2010added chemicals.\n                  <\/jats:p>","DOI":"10.1002\/smll.74198","type":"journal-article","created":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T09:36:57Z","timestamp":1782725817000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Rhodium Single\u2010Atom Decorated CeO\n                    <sub>2<\/sub>\n                    :Yb,Er\/Rh\u2010ZnIn\n                    <sub>2<\/sub>\n                    S\n                    <sub>4<\/sub>\n                    With Enhanced Photo\u2010Thermo\u2010Electric Effects for Efficient H\n                    <sub>2<\/sub>\n                    Evolution and Biomass 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