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Acrylamide (AA), depolymerized from polyacrylamide under natural conditions such as UV radiation and elevated temperatures, causes severe environmental pollution. Herein, in situ reconstructed Ag\u2010doped Ni\n                    <jats:sub>2<\/jats:sub>\n                    P nanosheets on Ni foam (CV\u2010Ag\u2010Ni\n                    <jats:sub>2<\/jats:sub>\n                    P\/NF) are developed as a bifunctional catalyst. This catalyst exhibits high activity for the AA oxidation reaction (AOR) while enabling energy\u2010efficient hydrogen evolution reaction (HER). After electrochemical operation, the initial zipper\u2010like morphology transforms into spherical features with interspersed rod\u2010like particles, providing a larger electrochemical surface area and more active sites. Particularly, a potential of 1.82\u00a0V delivers 100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in the two\u2010electrode AOR system. Remarkably, 79.3% AA removal was achieved after 24\u00a0h at 50\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Meanwhile, ethanol generated at the anode serves as a value\u2010added product. Density functional theory (DFT) calculations reveal that Ag atoms are the active sites for AA degradation and ethanol formation, with favorable adsorption energies. We propose a plausible AOR catalytic mechanism and reveal the key roles of Ag and Ni in H* adsorption and reduction of AA dehydrogenation energy, which offers a promising way of coupling AOR with HER to reduce energy consumption while producing high\u2010value products.\n                  <\/jats:p>","DOI":"10.1002\/smll.74237","type":"journal-article","created":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T12:02:01Z","timestamp":1784030521000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["In Situ Reconstruction of Ag\u2010Doped Ni\n                    <sub>2<\/sub>\n                    P Electrocatalyst for Hydrogen Evolution and Value\u2010Added Acrylamide Conversion"],"prefix":"10.1002","volume":"22","author":[{"given":"Dan","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"},{"name":"China Frontiers Science Center for Deep Ocean Multispheres and Earth System\/Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education Ocean University of China  238 Songling Road Qingdao P. R. China"},{"name":"Institute of Photochemistry and Photofunctional Materials University of Shanghai for Science and Technology  516 Jungong Road Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zeyi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingshen","family":"Meng","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carlos A.","family":"Triana","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shangkun","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0437-1661","authenticated-orcid":false,"given":"Yiming","family":"Li","sequence":"additional","affiliation":[{"name":"China Frontiers Science Center for Deep Ocean Multispheres and Earth System\/Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education Ocean University of China  238 Songling Road Qingdao P. 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