{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T17:24:05Z","timestamp":1786123445989,"version":"build-2736575974"},"reference-count":52,"publisher":"Wiley","issue":"44","license":[{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21973076"],"award-info":[{"award-number":["21973076"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,8]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>The sluggish room\u2010temperature curing kinetics and low\u2010temperature brittle failure of epoxy resins have long constrained their deployment in extreme environments. Although existing acceleration strategies can enhance curing rates, they are invariably accompanied by issues of intense exothermic heat release, cohesive embrittlement, and toxic emissions. Herein, inspired by mussel adhesive proteins, we present an interfacial\u2013bulk synergistic optimization strategy that leverages triazolinedione\u2013indole (TAD\u2013indole) click chemistry to construct a room\u2010temperature, second\u2010scale curable epoxy adhesive (RTIA). This strategy exploits the TAD\u2013indole cycloaddition reaction to form a high\u2010density C\u2013N crosslinked network, while concurrently endowing the crosslinking sites with dicarbonyl hydrogen bond acceptor functionalities, thereby achieving synchronous enhancement of cohesive strength and interfacial adhesion. The RTIA adhesive exhibits a dry shear strength of 9.42\u00a0MPa and retains 3.12\u00a0MPa after boiling water treatment, demonstrating stable performance across a broad temperature window from \u2212196\u00b0C to 80\u00b0C. Notably, the indole moieties confer intrinsic antibacterial properties that effectively suppress bacterial adhesion. This heat\u2010free curing mechanism fundamentally circumvents the adverse effects associated with conventional accelerators, enabling compatibility between instantaneous on\u2010site processing and deployment in extreme environments and thereby establishing a new paradigm for the design of high\u2010performance structural adhesives.<\/jats:p>","DOI":"10.1002\/smll.74255","type":"journal-article","created":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T13:35:30Z","timestamp":1782480930000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Fast Click Crosslinking Bio\u2010Inspired Adhesives With Tailored Hierarchical High Bonding and Exceptional Versatility"],"prefix":"10.1002","volume":"22","author":[{"given":"Yuhong","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory for Environment\u2010Friendly Energy Materials &amp; Inertial Confinement Fusion Energy Materials Key Laboratory of Sichuan Province &amp; School of Materials and Chemistry Southwest University of Science and Technology  Mianyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinping","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Environment\u2010Friendly Energy Materials &amp; Inertial Confinement Fusion Energy Materials Key Laboratory of Sichuan Province &amp; School of Materials and Chemistry Southwest University of Science and Technology  Mianyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Environment\u2010Friendly Energy Materials &amp; Inertial Confinement Fusion Energy Materials Key Laboratory of Sichuan Province &amp; School of Materials and Chemistry Southwest University of Science and Technology  Mianyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tengning","family":"Ma","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Environment\u2010Friendly Energy Materials &amp; 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