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Regarding this issue, we propose a \u201cthermal activation\u2013annealing synergy\u201d preparation strategy, focusing on revealing the decisive influence of the environment on strengthening intermolecular chain interactions. Compared with an open atmosphere, the confined high\u2010temperature and high\u2010pressure environment greatly promotes effective collisions and hydrogen bond formation between polymer chains (the molecular simulation g(r) value increases nearly tenfold), thereby constructing a denser physical network. Consequently, by integrating the rigid network of \u03ba\u2010carrageenan, the reinforcement from dynamic borate ester bonds, and the conductive\/photothermal functions of MXene, the \u03ba\u2010carrageenan\u2010poly(vinyl alcohol)\u2010MXene\/borax (KPM\u2010B) composite hydrogel is successfully prepared. This hydrogel exhibits high strength (compressive stress up to 2.4\u00a0MPa), high toughness (up to 567.3\u00a0kJ\/m\n                    <jats:sup>3<\/jats:sup>\n                    ), and outstanding fatigue resistance (3000 cycles). Based on these merits, we successfully apply it to full\u2010range monitoring from physiological signals (e.g., ECG) to large\u2010amplitude joint movements, and integrate it into a smart glove to achieve precise human\u2013machine interaction. This work provides a new paradigm for preparing high\u2010performance multifunctional hydrogels through environmental regulation.\n                  <\/jats:p>","DOI":"10.1002\/smll.74285","type":"journal-article","created":{"date-parts":[[2026,6,19]],"date-time":"2026-06-19T09:07:33Z","timestamp":1781860053000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Dynamically Bonded MXene\u2011Composite Hydrogel via Confined\u2011Space Gelation for Multimodal Sensing, Photothermal Response and Human\u2011Machine Interaction"],"prefix":"10.1002","volume":"22","author":[{"given":"Xin","family":"Guo","sequence":"first","affiliation":[{"name":"School of Petrochemical Engineering Jilin University of Chemical Technology  Jilin China"},{"name":"Shandong Provincial Engineering Research Center of Novel Pharmaceutical Excipients Sustained and Controlled Release Preparations School of Health &amp; Medicine Dezhou University  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