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Here, we present a paradigm shift that transforms corrosion from a destructive process into a useful synthesis tool. We demonstrate that a topologically close\u2010packed (TCP) intermetallic phase, when electrochemically activated in acid, naturally forms a self\u2010passivating, corrosion\u2010resistant amorphous oxide layer that establishes a durable and catalytically active interface. This corrosion\u2010built oxide layer enables exceptional hydrogen evolution reaction (HER) performance (90\u00a0mV at 10\u00a0mA\/cm\n                    <jats:sup>2<\/jats:sup>\n                    ) coupled with extended stability (&gt;200\u00a0h at 100\u00a0mA\/cm\n                    <jats:sup>2<\/jats:sup>\n                    ). Our work establishes \u201cpassivation engineering\u201d as a general design principle, leveraging guided corrosion to construct stable, active phases, offering a universal route to bridge the activity\u2013stability divide in non\u2010precious electrocatalysis.\n                  <\/jats:p>","DOI":"10.1002\/smll.74503","type":"journal-article","created":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T13:15:34Z","timestamp":1784034934000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Passivation Engineering Via Dynamic Construction of Amorphous Oxides on a Topologically Close\u2010Packed Phase for Sustainable Hydrogen Production"],"prefix":"10.1002","volume":"22","author":[{"given":"Xiang","family":"Gao","sequence":"first","affiliation":[{"name":"Department of Mechanical Engineering, College of Engineering City University of Hong Kong  Kowloon Hong Kong 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